Outputs (5)

Selective Photocatalytic Reduction of CO2 to CH4 over NU-1000 Metal-Organic Frameworks (2024)
Preprint / Working Paper
Korhonen, P., Thangamuthu, M., Castaldelli, E., Diego-Lopez, A., Weilhard, A., Clowes, R., O'Shea, J., Laybourn, A., & Lanterna, A. Selective Photocatalytic Reduction of CO2 to CH4 over NU-1000 Metal-Organic Frameworks

CO2 adsorption and its subsequent utilization represent a promising avenue for mitigating climate change. The conver-sion of CO2 into valuable and useful products like carbon monoxide, methane, and methanol offers significant economic benefits. Howev... Read More about Selective Photocatalytic Reduction of CO2 to CH4 over NU-1000 Metal-Organic Frameworks.

Unravelling synergistic effects in bi-metallic catalysts: deceleration of palladium–gold nanoparticle coarsening in the hydrogenation of cinnamaldehyde (2023)
Journal Article
Pinto, J., Weilhard, A., Norman, L. T., Lodge, R. W., Rogers, D. M., Gual, A., Cano, I., Khlobystov, A. N., Licence, P., & Alves Fernandes, J. (2023). Unravelling synergistic effects in bi-metallic catalysts: deceleration of palladium–gold nanoparticle coarsening in the hydrogenation of cinnamaldehyde. Catalysis Science and Technology, https://doi.org/10.1039/d3cy00289f

In this work, we demonstrate that the synergistic effect of PdAu nanoparticles (NPs) in hydrogenation reactions is not only related to high activity but also to their stability when compared to Pd mono-metallic NPs. To demonstrate this, a series of m... Read More about Unravelling synergistic effects in bi-metallic catalysts: deceleration of palladium–gold nanoparticle coarsening in the hydrogenation of cinnamaldehyde.

Low-Dimensional Metal-Organic Magnets as a Route toward the S = 2 Haldane Phase (2023)
Journal Article
Pitcairn, J., Iliceto, A., Cañadillas-Delgado, L., Fabelo, O., Liu, C., Balz, C., Weilhard, A., Argent, S. P., Morris, A. J., & Cliffe, M. J. (2023). Low-Dimensional Metal-Organic Magnets as a Route toward the S = 2 Haldane Phase. Journal of the American Chemical Society, 145(3), 1783-1792. https://doi.org/10.1021/jacs.2c10916

Metal-organic magnets (MOMs), modular magnetic materials where metal atoms are connected by organic linkers, are promising candidates for next-generation quantum technologies. MOMs readily form low-dimensional structures and so are ideal systems to r... Read More about Low-Dimensional Metal-Organic Magnets as a Route toward the S = 2 Haldane Phase.

Defect Etching in Carbon Nanotube Walls for Porous Carbon Nanoreactors: Implications for CO2 Sorption and the Hydrosilylation of Phenylacetylene (2022)
Journal Article
Astle, M. A., Weilhard, A., Rance, G. A., LeMercier, T. M., Stoppiello, C. T., Norman, L. T., Fernandes, J. A., & Khlobystov, A. N. (2022). Defect Etching in Carbon Nanotube Walls for Porous Carbon Nanoreactors: Implications for CO2 Sorption and the Hydrosilylation of Phenylacetylene. ACS Applied Nano Materials, 5(2), 2075-2086. https://doi.org/10.1021/acsanm.1c03803

A method of pore fabrication in the walls of carbon nanotubes has been developed, leading to porous nanotubes that have been filled with catalysts and utilized in liquid- and gas-phase reactions. Chromium oxide nanoparticles have been utilized as hig... Read More about Defect Etching in Carbon Nanotube Walls for Porous Carbon Nanoreactors: Implications for CO2 Sorption and the Hydrosilylation of Phenylacetylene.

Blurring the Boundary between Homogenous and Heterogeneous Catalysis using Palladium Nanoclusters with Dynamic Surfaces (2021)
Journal Article
Cano, I., Weilhard, A., Martin, C., Pinto, J., Lodge, R. W., Santos, A. R., Rance, G. A., Åhlgren, E. H., Jónsson, E., Yuan, J., Li, Z. Y., Licence, P., Khlobystov, A. N., & Fernandes, J. A. (2021). Blurring the Boundary between Homogenous and Heterogeneous Catalysis using Palladium Nanoclusters with Dynamic Surfaces. Nature Communications, 12(1), Article 4965. https://doi.org/10.1038/s41467-021-25263-6

Using a magnetron sputtering approach that allows size-controlled formation of nanoclusters, we have created palladium nanoclusters that combine the features of both heterogeneous and homogeneous catalysts. Here we report the atomic structures and el... Read More about Blurring the Boundary between Homogenous and Heterogeneous Catalysis using Palladium Nanoclusters with Dynamic Surfaces.