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Outputs (165)

Diagenesis in salt dome roof strata: barite - calcite assemblage in Jebel Madar, Oman (2017)
Journal Article
Vandeginste, V., Stehle, M. C., Jourdan, A.-L., Bradbury, H. J., Manning, C., & Cosgrove, J. W. (2017). Diagenesis in salt dome roof strata: barite - calcite assemblage in Jebel Madar, Oman. Marine and Petroleum Geology, 86, 408-425. https://doi.org/10.1016/j.marpetgeo.2017.06.008

Halokinesis causes a dynamic structural evolution with the development of faults and fractures, which can act as either preferential fluid pathways or barriers. Reconstructing reactive fluid flow in salt dome settings remains a challenge. This contri... Read More about Diagenesis in salt dome roof strata: barite - calcite assemblage in Jebel Madar, Oman.

Piperazine-based N4-type 16-membered macroheterocycles and their nickel(II) complexes (2017)
Journal Article
Vatsadze, S. Z., Krut’ko, D. P., Blake, A. J., & Mountford, P. (2017). Piperazine-based N4-type 16-membered macroheterocycles and their nickel(II) complexes. https://doi.org/10.6060/mhc161179v

Square-planar diamagnetic nickel(II) complexes 5a and 5b containing 16-membered diamino-diimino ligands were prepared from the corresponding open-chain complexes 2a and 2b via condensation with o-phthalic dialdehyde in methanol. The solid-state struc... Read More about Piperazine-based N4-type 16-membered macroheterocycles and their nickel(II) complexes.

An antiferromagnetically coupled heterometal Cu6Fe wheel (2017)
Journal Article
Saiki, R., Yoshida, N., Hoshino, N., Newton, G. N., Shiga, T., & Oshio, H. (2017). An antiferromagnetically coupled heterometal Cu6Fe wheel. Chemistry Letters, 46(8), https://doi.org/10.1246/cl.170365

A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6- (OH)2(OCH3)4](NO3)3¢6H2O (1¢6H2O) (H2L = 1-(2-pyridine) 3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals t... Read More about An antiferromagnetically coupled heterometal Cu6Fe wheel.

Interactions and stabilisation of acetone, sulfur dioxide and water with 1-octyl-3-methylimidazolium tetrafluoroborate [OMIM][BF4] at low temperatures (2017)
Journal Article
Buckley, M., Syres, K. L., & Jones, R. G. (in press). Interactions and stabilisation of acetone, sulfur dioxide and water with 1-octyl-3-methylimidazolium tetrafluoroborate [OMIM][BF4] at low temperatures. Faraday Discussions, 206, 475-495. https://doi.org/10.1039/C7FD00146K

The interactions between three small molecules, water (H2O), sulfur dioxide (SO2) and acetone ( (CH3)2CO ) with the ionic liquid (IL) 1-octyl-3-methylimidazolium tetrafluoroborate, [OMIM][BF4], have been determined using line of sight temperature pro... Read More about Interactions and stabilisation of acetone, sulfur dioxide and water with 1-octyl-3-methylimidazolium tetrafluoroborate [OMIM][BF4] at low temperatures.

Straightforward synthesis of 2- and 2,8-substituted tetracenes (2017)
Journal Article
Woodward, S., Ackermann, M., Ahirwar, S., Burroughs, L., Robert Garrett, M., Ritchie, J., …Woodward, P. (in press). Straightforward synthesis of 2- and 2,8-substituted tetracenes. Chemistry - A European Journal, https://doi.org/10.1002/chem.201701170

A simple regiospecific route to otherwise problematic substituted tetracenes is described. The diverse cores (E)- 1,2-Ar1CH2(HOCH2)C=C(CH2OH)I (Ar1 = Ph, 4-MePh, 4-MeOPh, 4-FPh) and (E)-1,2-I(HOCH2)C=C(CH2OH)I, accessed from ultra-low cost HOCH2C≡CCH... Read More about Straightforward synthesis of 2- and 2,8-substituted tetracenes.

Arylative intramolecular allylation of ketones with 1,3-enynes enabled by catalytic alkenyl-to-allyl 1,4-Rh(I) migration (2017)
Journal Article
Partridge, B. . M., Callingham, M., Lewis, W., & Lam, H. W. (2017). Arylative intramolecular allylation of ketones with 1,3-enynes enabled by catalytic alkenyl-to-allyl 1,4-Rh(I) migration. Angewandte Chemie International Edition, 56(25), https://doi.org/10.1002/anie.201703155

Alkenyl-to-allyl 1,4-Rh(I) migration enables the generation of nucleophilic allylrhodium(I) species by remote C–H activation. This new mode of reactivity was employed in the diastereoselective reaction of arylboron reagents with substrates containing... Read More about Arylative intramolecular allylation of ketones with 1,3-enynes enabled by catalytic alkenyl-to-allyl 1,4-Rh(I) migration.

Tuning the electronic environment of the anion by using binary ionic liquid mixtures (2017)
Journal Article
Men, S., & Licence, P. (2017). Tuning the electronic environment of the anion by using binary ionic liquid mixtures. Chemical Physics Letters, 681, https://doi.org/10.1016/j.cplett.2017.05.049

The electronic environment of the anion is tuned by using binary ionic liquid mixtures employing a com- mon anion and two cations with large difference in acidity. X-ray photoelectron spectroscopy is used to monitor the change of the electronic envir... Read More about Tuning the electronic environment of the anion by using binary ionic liquid mixtures.

An imaging photoelectron-photoion coincidence investigation of homochiral 2R,3R-butanediol clusters (2017)
Journal Article
Daly, S., Powis, I., Garcia, G. A., Tia, M., & Nahon, L. (2017). An imaging photoelectron-photoion coincidence investigation of homochiral 2R,3R-butanediol clusters. Journal of Chemical Physics, 147(1), Article 013937. https://doi.org/10.1063/1.4983139

We report an experimental investigation of homochiral cluster formation in seeded molecular beam expansions of (2R,3R)-butanediol. Synchrotron radiation VUV photoionization measurements have been performed using a double imaging electron-ion spectrom... Read More about An imaging photoelectron-photoion coincidence investigation of homochiral 2R,3R-butanediol clusters.