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Tuning the electronic environment of the anion by using binary ionic liquid mixtures

Men, Shuang; Licence, Peter

Authors

Shuang Men menshuang@hotmail.com

Peter Licence peter.licence@nottingham.ac.uk



Abstract

The electronic environment of the anion is tuned by using binary ionic liquid mixtures employing a com- mon anion and two cations with large difference in acidity. X-ray photoelectron spectroscopy is used to monitor the change of the electronic environment of the anion by measuring the binding energy of elements present in the anion. It is found that due to the large difference in acidity of the two cations, noticeable shifts can be observed for all anion-based components, no matter how basic the anion is.

Journal Article Type Article
Publication Date Aug 1, 2017
Journal Chemical Physics Letters
Print ISSN 0009-2614
Electronic ISSN 0009-2614
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 681
APA6 Citation Men, S., & Licence, P. (2017). Tuning the electronic environment of the anion by using binary ionic liquid mixtures. Chemical Physics Letters, 681, doi:10.1016/j.cplett.2017.05.049
DOI https://doi.org/10.1016/j.cplett.2017.05.049
Keywords Binary ionic liquid mixtures, Anion, XPS, Anion-based components
Publisher URL http://www.sciencedirect.com/science/article/pii/S0009261417304967
Copyright Statement Copyright information regarding this work can be found at the following address: http://eprints.nottingh.../end_user_agreement.pdf

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Tuning As Accepted 2017-3.pdf (321 Kb)
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Copyright Statement
Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf





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