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Strengthening the Magnetic Interactions in Pseudobinary First-Row Transition Metal Thiocyanates, M(NCS)2 (2020)
Journal Article
Bassey, E. N., Paddison, J. A., Keyzer, E. N., Lee, J., Manuel, P., da Silva, I., Dutton, S. E., Grey, C. P., & Cliffe, M. J. (2020). Strengthening the Magnetic Interactions in Pseudobinary First-Row Transition Metal Thiocyanates, M(NCS)2. Inorganic Chemistry, 59(16), 11627–11639. https://doi.org/10.1021/acs.inorgchem.0c01478

Understanding the effect of chemical composition on the strength of magnetic interactions is key to the design of magnets with high operating temperatures. The magnetic divalent first-row transition metal (TM) thiocyanates are a class of chemically s... Read More about Strengthening the Magnetic Interactions in Pseudobinary First-Row Transition Metal Thiocyanates, M(NCS)2.

The Structures of Ordered Defects in Thiocyanate Analogues of Prussian Blue (2020)
Journal Article
Cliffe, M., Keyzer, E., Bond, A., Astle, M. A., & Grey, C. (2020). The Structures of Ordered Defects in Thiocyanate Analogues of Prussian Blue. Chemical Science, 11(17), 4430-4438. https://doi.org/10.1039/D0SC01246G

We report the structures of six new divalent transition metal hexathiocyanatobismuthate frame-
works with the generic formula {M[Bi(SCN)6]2+x }x− {guest}x+, M = Mn, Co, Ni and Zn. These 3 frameworks are defective analogues of the perovskite-derived... Read More about The Structures of Ordered Defects in Thiocyanate Analogues of Prussian Blue.

SquidLab—A user-friendly program for background subtraction and fitting of magnetization data (2020)
Journal Article
Coak, M. J., Liu, C., Jarvis, D. M., Park, S., Cliffe, M. J., & Goddard, P. A. (2020). SquidLab—A user-friendly program for background subtraction and fitting of magnetization data. Review of Scientific Instruments, 91(2), Article 023901. https://doi.org/10.1063/1.5137820

We present an open-source program free to download for academic use with a full user-friendly graphical interface for performing flexible and robust background subtraction and dipole fitting on magnetization data. For magnetic samples with small mome... Read More about SquidLab—A user-friendly program for background subtraction and fitting of magnetization data.