Outputs (35)

Synthesis and Characterization of an f-Block Terminal Parent Imido [U═NH] Complex: A Masked Uranium(IV) Nitride (2014)
Journal Article
King, D. M., McMaster, J., Tuna, F., McInnes, E. J., Lewis, W., Blake, A. J., & Liddle, S. T. (2014). Synthesis and Characterization of an f-Block Terminal Parent Imido [U═NH] Complex: A Masked Uranium(IV) Nitride. Journal of the American Chemical Society, 136(15), 5619-5622. https://doi.org/10.1021/ja502405e

Deprotonation of [U(TrenTIPS)(NH2)] (1) [TrenTIPS = N(CH2CH2NSiPri3)3] with organoalkali metal reagents MR (M = Li, R = But; M = Na−Cs, R = CH2C6H5) afforded the imido-bridged dimers [{U-(TrenTIPS)(μ-N[H]M)}2] [M = L −Cs (2a−e)]. Treatmentof 2c (M =... Read More about Synthesis and Characterization of an f-Block Terminal Parent Imido [U═NH] Complex: A Masked Uranium(IV) Nitride.

Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes (2014)
Journal Article
Gardner, B. M., Balázs, G., Scheer, M., Tuna, F., McInnes, E. J., McMaster, J., Lewis, W., Blake, A. J., & Liddle, S. T. (2014). Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes. Angewandte Chemie International Edition, 53(17), 4484-4488. https://doi.org/10.1002/anie.201400798

Reaction of [U(TrenTIPS)(THF)][BPh4] (1; TrenTIPS=N{CH2CH2NSi(iPr)3}3) with NaPH2 afforded the novel f-block terminal parent phosphide complex [U(TrenTIPS)(PH2)] (2; U–P=2.883(2) Å). Treatment of 2 with one equivalent of KCH2C6H5 and two equivalents... Read More about Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes.

Bowing to the Pressure of π⋯π interactions: Bending of phenyl rings in a palladium(II) thioether crown complex (2013)
Journal Article
Wong, H. L., Allan, D. R., Champness, N. R., McMaster, J., Schröder, M., & Blake, A. J. (2013). Bowing to the Pressure of π⋯π interactions: Bending of phenyl rings in a palladium(II) thioether crown complex. Angewandte Chemie International Edition, 52(19), 5093-5095. https://doi.org/10.1002/anie.201209845

Compression of a parallel four-fold phenyl embrace involving two cations in [Pd([9]aneS3)(PPh3)2](PF6) 2 ([9]aneS3=1,4,7-trithiacyclononane) leads to π⋯π stacking interactions and concomitant pyramidalization at the ipso carbon atom of one of the phe... Read More about Bowing to the Pressure of π⋯π interactions: Bending of phenyl rings in a palladium(II) thioether crown complex.

Bis-thioether-substituted perylene diimides: Structural, electrochemical, and spectroelectrochemical properties (2013)
Journal Article
Slater, A. G., Davies, E. S., Argent, S. P., Lewis, W., Blake, A. J., McMaster, J., & Champness, N. R. (2013). Bis-thioether-substituted perylene diimides: Structural, electrochemical, and spectroelectrochemical properties. Journal of Organic Chemistry, 78(7), 2853-2862. https://doi.org/10.1021/jo400026r

The synthesis and separation of the 1,6- and 1,7- isomers of N,N′-bis(alkyl)diadamantylthio-3,4,9,10-perylenetetracarboxylic acid diimide are reported. Investigations of the structural, electrochemical, spectroscopic, and spectroelectrochemical prope... Read More about Bis-thioether-substituted perylene diimides: Structural, electrochemical, and spectroelectrochemical properties.

Bis-morpholine-substituted perylene bisimides: Impact of isomeric arrangement on electrochemical and spectroelectrochemical properties (2008)
Journal Article
Goretzki, G., Davies, E. S., Argent, S. P., Alsindi, W. Z., Blake, A. J., Warren, J. E., McMaster, J., & Champness, N. R. (2008). Bis-morpholine-substituted perylene bisimides: Impact of isomeric arrangement on electrochemical and spectroelectrochemical properties. Journal of Organic Chemistry, 73(22), 8808-8814. https://doi.org/10.1021/jo801557e

(Graph Presented) The synthesis and separation of the 1,6- and 1,7- isomers of N,N′-bis(n-butyl)dimorpholino-3,4:9,10-perylenetetracarboxylic acid bisimide are reported. Investigations of the electrochemical and spectroscopic, in particular, spectroe... Read More about Bis-morpholine-substituted perylene bisimides: Impact of isomeric arrangement on electrochemical and spectroelectrochemical properties.