Bowing to the Pressure of π⋯π interactions: Bending of phenyl rings in a palladium(II) thioether crown complex
(2013)
Journal Article
Wong, H. L., Allan, D. R., Champness, N. R., McMaster, J., Schröder, M., & Blake, A. J. (2013). Bowing to the Pressure of π⋯π interactions: Bending of phenyl rings in a palladium(II) thioether crown complex. Angewandte Chemie International Edition, 52(19), 5093-5095. https://doi.org/10.1002/anie.201209845
Compression of a parallel four-fold phenyl embrace involving two cations in [Pd([9]aneS3)(PPh3)2](PF6) 2 ([9]aneS3=1,4,7-trithiacyclononane) leads to π⋯π stacking interactions and concomitant pyramidalization at the ipso carbon atom of one of the phe... Read More about Bowing to the Pressure of π⋯π interactions: Bending of phenyl rings in a palladium(II) thioether crown complex.