Enhancement of CO2 uptake and selectivity in a metal-organic framework by incorporation of thiophene functionality

Bolotov, Vsevolod A.; Kovalenko, Konstantin A.; Samsonenko, Denis G.; Han, Xue; Zhang, Xinran; Smith, Gemma L.; McCormick, Laura; Teat, Simon J.; Yang, Sihai; Lennox, Matthew J.; Henley, Alice; Besley, Elena; Fedin, Vladimir P.; Dybtsev, Danil N.; Schröder, Martin

doi:10.1021/acs.inorgchem.8b00138

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Enhancement of CO2 uptake and selectivity in a metal-organic framework by incorporation of thiophene functionality (2018)
Journal Article
Bolotov, V. A., Kovalenko, K. A., Samsonenko, D. G., Han, X., Zhang, X., Smith, G. L., McCormick, L., Teat, S. J., Yang, S., Lennox, M. J., Henley, A., Besley, E., Fedin, V. P., Dybtsev, D. N., & Schröder, M. (2018). Enhancement of CO2 uptake and selectivity in a metal-organic framework by incorporation of thiophene functionality. Inorganic Chemistry, 57(9), https://doi.org/10.1021/acs.inorgchem.8b00138

The complex [Zn2(tdc)2dabco] (H2tdc = thiophene-2,5-dicarboxylic acid; dabco = 1,4-diazabicyclooctane) shows a remarkable increase in CO2 uptake and CO2/N2 selectivity compared to the non-thiophene analogue [Zn2(bdc)2dabco] (H2bdc = benzene-1,4-dica... Read More about Enhancement of CO2 uptake and selectivity in a metal-organic framework by incorporation of thiophene functionality.