Synthesis and control of crosslinked poly(acrylic acid) based viscosity modifiers using dense phase carbon dioxide as a solvent

Alexander, W.H.; Wickson, J.; Duncan, J.; Carmichael, K.; Irvine, D.J.; Howdle, S.M.

doi:10.1016/j.supflu.2018.05.003

All Outputs (4)

New renewably-sourced polyesters from limonene-derived monomers (2018)
Journal Article
Thomsett, M. R., Moore, J. C., Buchard, A., Stockman, R. A., & Howdle, S. M. (2019). New renewably-sourced polyesters from limonene-derived monomers. Green Chemistry, 21(1), 149-156. https://doi.org/10.1039/c8gc02957a

The functionalisation of limonene has enabled the synthesis of two renewably-sourced monomers for the formation of terpene-derived polyesters. Three methods for the synthesis of the novel hydroxy-acid 6 are reported and their green-credentials scruti... Read More about New renewably-sourced polyesters from limonene-derived monomers.

Sustainable synthesis and precise characterisation of bio-based star polycaprolactone synthesised with a metal catalyst and with lipase (2018)
Journal Article
Baheti, P., Gimello, O., Bouilhac, C., Lacroix-Desmazes, P., & Howdle, S. M. (2018). Sustainable synthesis and precise characterisation of bio-based star polycaprolactone synthesised with a metal catalyst and with lipase. Polymer Chemistry, 9(47), 5594-5607. https://doi.org/10.1039/c8py01266k

Bio-based building blocks and sustainable synthesis pathways were used to synthesise star-shaped polymers composed of a D-sorbitol core and polycaprolactone arms by ring opening polymerisation (ROP). The use of volatile organic solvents was avoided a... Read More about Sustainable synthesis and precise characterisation of bio-based star polycaprolactone synthesised with a metal catalyst and with lipase.

A facile route to bespoke macro- and mesoporous block copolymer microparticles (2018)
Journal Article
He, G., Bennett, T. M., Alauhdin, M., Fay, M. W., Liu, X., Schwab, S. T., Sun, C.-G., & Howdle, S. M. (in press). A facile route to bespoke macro- and mesoporous block copolymer microparticles. Polymer Chemistry, 9(27), https://doi.org/10.1039/c8py00707a

We report a facile and versatile strategy for the bespoke fabrication of macro- and mesoporous block copolymer microparticles. A clean synthetic route, RAFT dispersion polymerisation in supercritical carbon dioxide (scCO2), is used to generate block... Read More about A facile route to bespoke macro- and mesoporous block copolymer microparticles.

Synthesis and control of crosslinked poly(acrylic acid) based viscosity modifiers using dense phase carbon dioxide as a solvent (2018)
Journal Article
Alexander, W., Wickson, J., Duncan, J., Carmichael, K., Irvine, D., & Howdle, S. (2018). Synthesis and control of crosslinked poly(acrylic acid) based viscosity modifiers using dense phase carbon dioxide as a solvent. Journal of Supercritical Fluids, 139, 38-44. https://doi.org/10.1016/j.supflu.2018.05.003

We investigate the clean synthesis of a cross-linked poly(acrylic acid) viscosity modifier using supercritical CO2 to replace more hazardous volatile organic solvents that are typically used for this process. The polymers were analysed by aqueous swe... Read More about Synthesis and control of crosslinked poly(acrylic acid) based viscosity modifiers using dense phase carbon dioxide as a solvent.