Heterobimetallic [NiFe] complexes containing mixedCO/CN− ligands: analogs of the active site of the [NiFe]hydrogenases

Perotto, Carlo U.; Sodipo, Charlene L.; Jones, Graham J.; Tidey, Jeremiah P.; Blake, Alexander J.; Lewis, William; Davies, E. Stephen; McMaster, Jonathan; Schröder, Martin

doi:10.1021/acs.inorgchem.7b02905

All Outputs (6)

Thionated perylene diimide–phenothiazine dyad: synthesis, structure, and electrochemical studies (2018)
Journal Article

Perylene diimides (PDIs) are promising candidates for n-type semiconductor materials and, thus, for use in organic electronics. Thionation of the imide moiety provides an e?cient strategy to control the donor?acceptor gap of these types of compounds... Read More about Thionated perylene diimide–phenothiazine dyad: synthesis, structure, and electrochemical studies.

Selective reduction and homologation of carbon monoxide by organometallic iron complexes (2018)
Journal Article

Carbon monoxide is a key C1 feedstock for the industrial production of hydrocarbons, where it is used to make millions of tonnes of chemicals, fuels, and solvents per annum. Many transition metal complexes can coordinate CO2 but the formation of new... Read More about Selective reduction and homologation of carbon monoxide by organometallic iron complexes.

Influence of hydrogen-bonding interactions on nuclearity and structure of palladium tiara-like complexes (2018)
Journal Article

The role of intramolecular hydrogen-bonding interactions upon the nuclearity of palladium tiara-like complexes is reported herein. The synthesis of three palladium tiaras is described with three related thiolate ligands that vary in their hydrogen-bo... Read More about Influence of hydrogen-bonding interactions on nuclearity and structure of palladium tiara-like complexes.

Self-assembly of chiral-at-end diketopyrrolopyrroles: symmetry dependent solution and film optical activity and photovoltaic performanace (2018)
Journal Article

Chiral thiophene-diketopyrrolopyrrole derivatives have been synthesised to investigate the potential of stereochemistry and symmetry as a means of modulating properties by influencing self-assembly of these purely organic materials. In particular, de... Read More about Self-assembly of chiral-at-end diketopyrrolopyrroles: symmetry dependent solution and film optical activity and photovoltaic performanace.

Characterisation of redox states of metal-organic frameworks by growth on modified thin-film electrodes (2018)
Journal Article

The application of metal-organic framework (MOF) materials in electrochemical and electrochromic devices remain rare. One of the main reasons for this is the inability to readily access their detailed electrochemistry. The inherent insolubility of th... Read More about Characterisation of redox states of metal-organic frameworks by growth on modified thin-film electrodes.

Heterobimetallic [NiFe] complexes containing mixedCO/CN− ligands: analogs of the active site of the [NiFe]hydrogenases (2018)
Journal Article

The development of synthetic analogs of the active sites of [NiFe] hydrogenases remains challenging and, in spite of the number of complexes featuring a [NiFe] center, those featuring CO and CN− ligands at the Fe center are under-represented. We repo... Read More about Heterobimetallic [NiFe] complexes containing mixedCO/CN− ligands: analogs of the active site of the [NiFe]hydrogenases.