Skip to main content

Research Repository

Advanced Search

All Outputs (2)

Critical analysis of the limitations of Bleaney's theory of magnetic anisotropy in paramagnetic lanthanide coordination complexes (2014)
Journal Article
Funk, A. M., Finney, K.-L. N. A., Harvey, P., Kenwright, A. M., Neil, E. R., Rogers, N. J., …Parker, D. (2014). Critical analysis of the limitations of Bleaney's theory of magnetic anisotropy in paramagnetic lanthanide coordination complexes. Chemical Science, 6(3), 1655-1662. https://doi.org/10.1039/c4sc03429e

The origins of the breakdown of Bleaney's theory of magnetic anisotropy are described, based on an analysis of eleven different complexes of the second half of the 4f elements that form isostructural series. An examination of the chemical shift and r... Read More about Critical analysis of the limitations of Bleaney's theory of magnetic anisotropy in paramagnetic lanthanide coordination complexes.

Ratiometric detection of enzyme turnover and flavin reduction using rare-earth upconverting phosphors (2014)
Journal Article
Harvey, P., Oakland, C., Driscoll, M. D., Hay, S., & Natrajan, L. S. (2014). Ratiometric detection of enzyme turnover and flavin reduction using rare-earth upconverting phosphors. Dalton Transactions, 43(14), 5265-5268. https://doi.org/10.1039/c4dt00356j

Gd4O2S:Yb:Tm rare-earth upconversion phosphors have been utilised to monitor the redox behaviour of flavin mononucleotide and report on the turnover of a flavo-protein, (pentaerythritol tetranitrate reductase). The presence of two bands separated by... Read More about Ratiometric detection of enzyme turnover and flavin reduction using rare-earth upconverting phosphors.