All Outputs (4)

Carboxylic acid functionalized spin-crossover iron(II) grids for tunable switching and hybrid electrode fabrication (2018)
Journal Article
Shiga, T., Sato, Y., Tachibana, M., Sato, H., Matsumoto, T., Sagayama, H., …Oshio, H. (2018). Carboxylic acid functionalized spin-crossover iron(II) grids for tunable switching and hybrid electrode fabrication. Inorganic Chemistry, 57(22), 14013-14017. https://doi.org/10.1021/acs.inorgchem.8b01856

Two carboxyl-substituted iron(II) grids, one protonated, [Fe4(HL)4](BF4)4·4MeCN·AcOEt (1), and the other deprotonated, [Fe4(L)4]·DMSO·EtOH (2), where H2L = 4-{4,5-bis[6-(3,5-dimethylpyrazol-1-yl)pyrid-2-yl]-1H-imidazol-2-yl}benzoic acid, were synthes... Read More about Carboxylic acid functionalized spin-crossover iron(II) grids for tunable switching and hybrid electrode fabrication.

Tuning the electronic structure of organic–inorganic hybrid polyoxometalates: The crucial role of the covalent linkage (2018)
Journal Article
Kibler, A. J., & Newton, G. N. (2018). Tuning the electronic structure of organic–inorganic hybrid polyoxometalates: The crucial role of the covalent linkage. Polyhedron, 154, 1-20. https://doi.org/10.1016/j.poly.2018.06.027

The covalent organofunctionalization of polyoxometalates (POMs) has been widely used to both control and enhance their redox properties, particularly for applications in catalysis, energy storage, optics and molecular magnetism. The design of such sy... Read More about Tuning the electronic structure of organic–inorganic hybrid polyoxometalates: The crucial role of the covalent linkage.

Cobalt complexes with redox-active anthraquinone-type ligands (2018)
Journal Article
Shiga, T., Kumamaru, R., Newton, G. N., & Oshio, H. (2018). Cobalt complexes with redox-active anthraquinone-type ligands. Dalton Transactions, 47(23), https://doi.org/10.1039/C8DT00586A

Three anthraquinone-type multidentate ligands, HL1-3 (HL = 2-R-1H-anthra[1,2-d]imidazole6,11-dione, HL1; R = (2-pyridyl), HL2; R = (4,6-dimethyl-2-pyridyl), HL3; R = (6-methoxy-2pyridyl)), were prepared, and their complexation behaviour were investig... Read More about Cobalt complexes with redox-active anthraquinone-type ligands.

Pre-programmed self-assembly of polynuclear clusters (2018)
Journal Article
Shiga, T., Newton, G. N., & Oshio, H. (in press). Pre-programmed self-assembly of polynuclear clusters. Dalton Transactions, https://doi.org/10.1039/C8DT00822A

This perspective reviews our recent efforts towards the self-assembly of polynuclear clusters with ditopic and tritopic multidentate ligands HL1 (2-phenyl-4,5-bis{6-(3,5-dimethylpyrazol-1-yl)pyrid-2-yl}-1H-imidazole) and H2L2 (2,6-bis-[5-(2-pyridinyl... Read More about Pre-programmed self-assembly of polynuclear clusters.