All Outputs (2)

Synthesis, crystal structures and magnetic properties of composites incorporating an Fe(II) spin crossover complex and polyoxometalates (2017)
Journal Article
Kuramochi, S., Shiga, T., Cameron, J. M., Newton, G. N., & Oshio, H. (2017). Synthesis, crystal structures and magnetic properties of composites incorporating an Fe(II) spin crossover complex and polyoxometalates. Inorganics, 5(3), Article 48. https://doi.org/10.3390/inorganics5030048

[Fe(dppOH)2]2+ (dppOH = 2,6-di(pyrazol-1-yl)-4-(hydroxymethyl)pyridine) is known to show spin crossover (SCO) behavior and light-induced excited spin state transitions (LIESST). Here, we show that the SCO properties of the [Fe(dppOH)2]2+ complex can... Read More about Synthesis, crystal structures and magnetic properties of composites incorporating an Fe(II) spin crossover complex and polyoxometalates.

An antiferromagnetically coupled heterometal Cu6Fe wheel (2017)
Journal Article
Saiki, R., Yoshida, N., Hoshino, N., Newton, G. N., Shiga, T., & Oshio, H. (2017). An antiferromagnetically coupled heterometal Cu6Fe wheel. Chemistry Letters, 46(8), https://doi.org/10.1246/cl.170365

A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6- (OH)2(OCH3)4](NO3)3¢6H2O (1¢6H2O) (H2L = 1-(2-pyridine) 3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals t... Read More about An antiferromagnetically coupled heterometal Cu6Fe wheel.