An Expanded 2D Fused Aromatic Network with 90-Ring Hexagons

Riaño, Alberto; Strutyński, Karol; Liu, Meng; Stoppiello, Craig T.; Lerma‐Berlanga, Belén; Saeki, Akinori; Martí‐Gastaldo, Carlos; Khlobystov, Andrei N.; Valenti, Giovanni; Paolucci, Francesco; Melle‐Franco, Manuel; Mateo-Alonso, Aurelio

Abstract

Two-dimensional fused aromatic networks (2D FANs) have emerged as a highly versatile alternative to holey graphene. The synthesis of 2D FANs with increasingly larger lattice dimensions will enable new application perspectives. However, the synthesis of larger analogues is mostly limited by lack of appropriate monomers and methods. Herein, we describe the synthesis, characterisation and properties of an expanded 2D FAN with 90-ring hexagons, which exceed the largest 2D FAN lattices reported to date.

Citation

Riaño, A., Strutyński, K., Liu, M., Stoppiello, C. T., Lerma‐Berlanga, B., Saeki, A., …Mateo-Alonso, A. (2022). An Expanded 2D Fused Aromatic Network with 90-Ring Hexagons. Angewandte Chemie International Edition, 61(2), Article e202113657. https://doi.org/10.1002/anie.202113657

• Journal Article Type: Article
• Acceptance Date: Nov 8, 2021
• Online Publication Date: Dec 2, 2021
• Publication Date: Jan 10, 2022
• Deposit Date: Jan 4, 2022
• Publicly Available Date: Jan 5, 2022
• Journal: Angewandte Chemie - International Edition
• Print ISSN: 1433-7851
• Electronic ISSN: 1521-3773
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 61
• Issue: 2
• Article Number: e202113657
• DOI: https://doi.org/10.1002/anie.202113657
• Keywords: General Chemistry; Catalysis
• Public URL: https://nottingham-repository.worktribe.com/output/7162844
• Publisher URL: https://onlinelibrary.wiley.com/doi/10.1002/anie.202113657