π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons

Mart�nez?Abad�a, Marta; Struty?ski, Karol; Lerma?Berlanga, Bel�n; Stoppiello, Craig T.; Khlobystov, Andrei N.; Mart�?Gastaldo, Carlos; Saeki, Akinori; Melle?Franco, Manuel; Mateo?Alonso, Aurelio

Abstract

Three-dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic (D3d) nodes. Such 3D COFs are six-fold interpenetrated as the result of interframework π-stacking, which enable charge transport properties that are not expected for 3D COFs.

Citation

Martínez‐Abadía, M., Strutyński, K., Lerma‐Berlanga, B., Stoppiello, C. T., Khlobystov, A. N., Martí‐Gastaldo, C., …Mateo‐Alonso, A. (2021). π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons. Angewandte Chemie International Edition, 60(18), 9941-9946. https://doi.org/10.1002/anie.202100434

• Journal Article Type: Article
• Acceptance Date: Feb 8, 2021
• Online Publication Date: Mar 18, 2021
• Publication Date: Apr 26, 2021
• Deposit Date: Jun 3, 2021
• Publicly Available Date: Mar 19, 2022
• Journal: Angewandte Chemie International Edition
• Print ISSN: 1433-7851
• Electronic ISSN: 1521-3773
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 60
• Issue: 18
• Pages: 9941-9946
• DOI: https://doi.org/10.1002/anie.202100434
• Keywords: General Chemistry; Catalysis
• Public URL: https://nottingham-repository.worktribe.com/output/5421340
• Publisher URL: https://onlinelibrary.wiley.com/doi/10.1002/anie.202100434
• Additional Information: This is the peer reviewed version of the following article: M. Martínez-Abadía, K. Strutyński, B. Lerma-Berlanga, C. T. Stoppiello, A. N. Khlobystov, C. Martí-Gastaldo, A. Saeki, M. Melle-Franco, A. Mateo-Alonso, Angew. Chem. Int. Ed. 2021, 60, 9941., which has been published in final form at https://doi.org/10.1002/anie.202100434. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.