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Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(I) migration

Ruscoe, Rebecca E.; Callingham, Michael; Baker, Joshua A.; Korkis, Stamatis E; Lam, Hon Wai

Authors

Rebecca E. Ruscoe

Michael Callingham

Joshua A. Baker

Stamatis E Korkis

HON LAM Hon.Lam@nottingham.ac.uk
Professor of Sustainable Chemistry



Abstract

A novel multicomponent coupling reaction involving the iridium-catalyzed 1,5-difunctionalization of 1,3-enynes with arylboronic acids and triazinanes is described. A key step in this 1,5-(aryl)aminomethylation reaction is the alkenyl-to-allyl 1,4-iridium(I) migration.

Journal Article Type Article
Publication Date Dec 14, 2018
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 55
Issue 6
Pages 838-841
APA6 Citation Ruscoe, R. E., Callingham, M., Baker, J. A., Korkis, S. E., & Lam, H. W. (2018). Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(I) migration. Chemical Communications, 55(6), 838-841. https://doi.org/10.1039/c8cc09238a
DOI https://doi.org/10.1039/c8cc09238a
Keywords Materials Chemistry; Electronic, Optical and Magnetic Materials; General Chemistry; Surfaces, Coatings and Films; Metals and Alloys; Ceramics and Composites; Catalysis
Publisher URL https://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC09238A#!divAbstract

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