Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(I) migration

Ruscoe, Rebecca E.; Callingham, Michael; Baker, Joshua A.; Korkis, Stamatis E; Lam, Hon Wai

Abstract

A novel multicomponent coupling reaction involving the iridium-catalyzed 1,5-difunctionalization of 1,3-enynes with arylboronic acids and triazinanes is described. A key step in this 1,5-(aryl)aminomethylation reaction is the alkenyl-to-allyl 1,4-iridium(I) migration.

Citation

Ruscoe, R. E., Callingham, M., Baker, J. A., Korkis, S. E., & Lam, H. W. (2018). Iridium-catalyzed 1,5-(aryl)aminomethylation of 1,3-enynes by alkenyl-to-allyl 1,4-iridium(I) migration. Chemical Communications, 55(6), 838-841. https://doi.org/10.1039/c8cc09238a

• Journal Article Type: Article
• Acceptance Date: Dec 14, 2018
• Online Publication Date: Dec 14, 2018
• Publication Date: Dec 14, 2018
• Deposit Date: Dec 14, 2018
• Publicly Available Date: Dec 15, 2019
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 55
• Issue: 6
• Pages: 838-841
• DOI: https://doi.org/10.1039/c8cc09238a
• Keywords: Materials Chemistry; Electronic, Optical and Magnetic Materials; General Chemistry; Surfaces, Coatings and Films; Metals and Alloys; Ceramics and Composites; Catalysis
• Public URL: https://nottingham-repository.worktribe.com/output/1416551
• Publisher URL: https://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC09238A#!divAbstract