Outputs (146)

Defect Etching in Carbon Nanotube Walls for Porous Carbon Nanoreactors: Implications for CO2 Sorption and the Hydrosilylation of Phenylacetylene (2022)
Journal Article
Astle, M. A., Weilhard, A., Rance, G. A., LeMercier, T. M., Stoppiello, C. T., Norman, L. T., …Khlobystov, A. N. (2022). Defect Etching in Carbon Nanotube Walls for Porous Carbon Nanoreactors: Implications for CO2 Sorption and the Hydrosilylation of Phenylacetylene. ACS Applied Nano Materials, 5(2), 2075-2086. https://doi.org/10.1021/acsanm.1c03803

A method of pore fabrication in the walls of carbon nanotubes has been developed, leading to porous nanotubes that have been filled with catalysts and utilized in liquid- and gas-phase reactions. Chromium oxide nanoparticles have been utilized as hig... Read More about Defect Etching in Carbon Nanotube Walls for Porous Carbon Nanoreactors: Implications for CO2 Sorption and the Hydrosilylation of Phenylacetylene.

An experimental and theoretical study of the Kr 3d correlation satellites (2022)
Journal Article
Kiselev, M. D., Reinhardt, M., Patanen, M., Kivimaki, A. E., Powis, I., Zatsarinny, O., …Holland, D. M. P. (2022). An experimental and theoretical study of the Kr 3d correlation satellites. Journal of Physics B: Atomic, Molecular and Optical Physics, 55(5), Article 055002. https://doi.org/10.1088/1361-6455/ac521a

The Kr 3d correlation satellites have been studied experimentally by using plane polarized synchrotron radiation to record polarization dependent photoelectron spectra (PES), and theoretically by employing the R-matrix method to calculate photoioniza... Read More about An experimental and theoretical study of the Kr 3d correlation satellites.

Correction to “Bespoke 3D-Printed Polydrug Implants Created via Microstructural Control of Oligomers” (2022)
Journal Article
Ruiz-Cantu, L., Trindade, G. F., Taresco, V., Zhou, Z., He, Y., Burroughs, L., …Wildman, R. D. (2022). Correction to “Bespoke 3D-Printed Polydrug Implants Created via Microstructural Control of Oligomers”. ACS Applied Materials and Interfaces, 14(6), 8654. https://doi.org/10.1021/acsami.2c00035

The chemical structure of the drug trandolapril has been corrected in Figure 4c. The conclusions of the work have not been affected by this correction. (Figure present).

Selective photoinduced charge separation in perylenediimide-pillar[5]arene rotaxanes (2022)
Journal Article
Pearce, N., Reynolds, K. E. A., Kayal, S., Sun, X. Z., Davies, E. S., Malagreca, F., …Champness, N. R. (2022). Selective photoinduced charge separation in perylenediimide-pillar[5]arene rotaxanes. Nature Communications, 13(1), Article 415. https://doi.org/10.1038/s41467-022-28022-3

The ability to control photoinduced charge transfer within molecules represents a major challenge requiring precise control of the relative positioning and orientation of donor and acceptor groups. Here we show that such photoinduced charge transfer... Read More about Selective photoinduced charge separation in perylenediimide-pillar[5]arene rotaxanes.

Borane Adducts of Aromatic Phosphorus Heterocycles: Synthesis, Crystallographic Characterization and Reactivity of a Phosphinine‐B(C 6 F 5 ) 3 Lewis Pair (2022)
Journal Article
Lin, J., Wossidlo., F., Coles, N. T., Weber, M., Steinhauer, S., Böttcher, T., & Müller, C. (2022). Borane Adducts of Aromatic Phosphorus Heterocycles: Synthesis, Crystallographic Characterization and Reactivity of a Phosphinine‐B(C 6 F 5 ) 3 Lewis Pair. Chemistry - A European Journal, 28(7), Article e202104135. https://doi.org/10.1002/chem.202104135

A phosphinine-borane adduct of a Me3Si-functionalized phosphinine and the Lewis acid B(C6F5)3 has been synthesized and characterized crystallographically for the first time. The reaction strongly depends on the nature of the substituents in the α-pos... Read More about Borane Adducts of Aromatic Phosphorus Heterocycles: Synthesis, Crystallographic Characterization and Reactivity of a Phosphinine‐B(C 6 F 5 ) 3 Lewis Pair.

In situ silane activation enables catalytic reduction of carboxylic acids (2022)
Journal Article
Stoll, E. L., Barber, T., Hirst, D. J., & Denton, R. M. (2022). In situ silane activation enables catalytic reduction of carboxylic acids. Chemical Communications, 58(21), 3509-3512. https://doi.org/10.1039/D1CC03396D

We describe a catalytic system for the conversion of carboxylic acids into alcohols using substoichiometric zinc acetate and N-methyl morpholine, in combination with phenylsilane as the nominal terminal reductant. Reaction monitoring by 19F NMR spect... Read More about In situ silane activation enables catalytic reduction of carboxylic acids.

Effect of Oriented Electric Fields on Biologically Relevant Iron–Sulfur Clusters: Tuning Redox Reactivity for Catalysis (2022)
Journal Article
Gaughan, S. J. H., Hirst, J. D., Croft, A. K., & Jäger, C. M. (2022). Effect of Oriented Electric Fields on Biologically Relevant Iron–Sulfur Clusters: Tuning Redox Reactivity for Catalysis. Journal of Chemical Information and Modeling, 62(3), 591-601. https://doi.org/10.1021/acs.jcim.1c00791

Enzyme-based iron-sulfur clusters, exemplified in families such as hydrogenases, nitrogenases, and radical S-Adenosylmethionine enzymes, feature in many essential biological processes. The functionality of biological iron-sulfur clusters extends beyo... Read More about Effect of Oriented Electric Fields on Biologically Relevant Iron–Sulfur Clusters: Tuning Redox Reactivity for Catalysis.

Reactive Jetting of High Viscosity Nanocomposites for Dielectric Elastomer Actuation (2022)
Journal Article
Malas, A., Saleh, E., Giménez‐López, M. D. C., Rance, G. A., Helps, T., Taghavi, M., …Goodridge, R. D. (2022). Reactive Jetting of High Viscosity Nanocomposites for Dielectric Elastomer Actuation. Advanced Materials Technologies, 7(6), Article 2101111. https://doi.org/10.1002/admt.202101111

The layer-by-layer nature of additive manufacturing is well matched to the layer construction of stacked dielectric actuators, with inkjet printing offering a unique opportunity due to its droplet-on-demand capability, suitable for multi-material pro... Read More about Reactive Jetting of High Viscosity Nanocomposites for Dielectric Elastomer Actuation.

Enantioselective “clip-cycle” synthesis of di-, tri- and spiro-substituted tetrahydropyrans (2022)
Journal Article
Alomari, K., Sai Pavan Chakravarthy, N., Duchadeau, B., Ermanis, K., & Clarke, P. A. (2022). Enantioselective “clip-cycle” synthesis of di-, tri- and spiro-substituted tetrahydropyrans. Organic and Biomolecular Chemistry, 20(6), 1181-1185. https://doi.org/10.1039/d2ob00023g

ω-Unsaturated alcohols were “clipped” via alkene metathesis to a thioester activating group, which was followed by a chiral phosphoric acid catalyzed intramolecular oxa-Michael cyclization to yield tetrahydropyrans and spiro-tetrahydropyrans with exc... Read More about Enantioselective “clip-cycle” synthesis of di-, tri- and spiro-substituted tetrahydropyrans.

Modulating the porosity of carbons for improved adsorption of hydrogen, carbon dioxide, and methane: a review (2022)
Journal Article
Blankenship, L. S., & Mokaya, R. (2022). Modulating the porosity of carbons for improved adsorption of hydrogen, carbon dioxide, and methane: a review. Materials Advances, 3(4), 1905-1930. https://doi.org/10.1039/d1ma00911g

Porous carbons provide a low-cost route to a highly stable material for the adsorption of various gases. In particular, activated carbons (ACs) and zeolite templated carbons (ZTCs) show promise in their ability to capture and store environmentally re... Read More about Modulating the porosity of carbons for improved adsorption of hydrogen, carbon dioxide, and methane: a review.