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Mechanistic Insights on the Semihydrogenation of Alkynes over Different Nanostructured Photocatalysts (2021)
Journal Article
Wang, B., Lanterna, A. E., & Scaiano, J. C. (2021). Mechanistic Insights on the Semihydrogenation of Alkynes over Different Nanostructured Photocatalysts. ACS Catalysis, 11(7), 4230-4238. https://doi.org/10.1021/acscatal.0c05233

A single molecule microscopy study of the interaction of dye-modified alkanes, alkenes and alkynes with nanostructured catalysts based on TiO 2 reveals significant differences in the desorption kinetics of the probe molecules depending on the chemica... Read More about Mechanistic Insights on the Semihydrogenation of Alkynes over Different Nanostructured Photocatalysts.

π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons (2021)
Journal Article
Martínez‐Abadía, M., Strutyński, K., Lerma‐Berlanga, B., Stoppiello, C. T., Khlobystov, A. N., Martí‐Gastaldo, C., …Mateo‐Alonso, A. (2021). π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons. Angewandte Chemie International Edition, 60(18), 9941-9946. https://doi.org/10.1002/anie.202100434

Three-dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic (D3d) nodes. Such 3D COFs are six-fold interpenetrated as the result of... Read More about π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons.

A Guide to Directing Group Removal: 8‐Aminoquinoline (2021)
Journal Article
Fitzgerald, L. S., & O'Duill, M. L. (2021). A Guide to Directing Group Removal: 8‐Aminoquinoline. Chemistry - A European Journal, 27(33), 8411-8436. https://doi.org/10.1002/chem.202100093

The use of directing groups allows high levels of selectivity to be achieved in transition metal‐catalyzed transformations. Efficient removal of these auxiliaries after successful functionalization, however, can be very challenging. This review provi... Read More about A Guide to Directing Group Removal: 8‐Aminoquinoline.

Enantio-Complementary Continuous-Flow Synthesis of 2-Aminobutane Using Covalently Immobilized Transaminases (2021)
Journal Article
Heckmann, C. M., Dominguez, B., & Paradisi, F. (2021). Enantio-Complementary Continuous-Flow Synthesis of 2-Aminobutane Using Covalently Immobilized Transaminases. ACS Sustainable Chemistry and Engineering, 9(11), 4122-4129. https://doi.org/10.1021/acssuschemeng.0c09075

Chiral amines are a common feature of many active pharmaceutical ingredients. The synthesis of very small chiral amines is particularly challenging, even via biocatalytic routes, as the level of discrimination between similarly sized R-groups must be... Read More about Enantio-Complementary Continuous-Flow Synthesis of 2-Aminobutane Using Covalently Immobilized Transaminases.

Enantioselective Nickel‐Catalyzed anti ‐Arylmetallative Cyclizations onto Acyclic Ketones (2021)
Journal Article
Green, H., Argent, S., & Lam, H. (2021). Enantioselective Nickel‐Catalyzed anti ‐Arylmetallative Cyclizations onto Acyclic Ketones. Chemistry - A European Journal, 27(19), 5897-5900. https://doi.org/10.1002/chem.202100143

Domino reactions involving nickel‐catalyzed additions of (hetero)arylboronic acids to alkynes, followed by cyclization of the alkenylnickel intermediates onto tethered acyclic ketones to give chiral tertiary‐alcohol‐containing products in high enanti... Read More about Enantioselective Nickel‐Catalyzed anti ‐Arylmetallative Cyclizations onto Acyclic Ketones.

Vibronic interaction in trans-dichloroethene studied by vibration- and angle-resolved photoelectron spectroscopy using 19–90 eV photon energy (2021)
Journal Article
Duran, A. T., Powis, I., Holland, D. M. P., Nicolas, C., Bozek, J., Trofimov, A. B., …Skitnevskaya, A. D. (2021). Vibronic interaction in trans-dichloroethene studied by vibration- and angle-resolved photoelectron spectroscopy using 19–90 eV photon energy. Journal of Chemical Physics, 154(9), Article 094303. https://doi.org/10.1063/5.0040049

Valence photoelectron spectra and photoelectron angular distributions of trans-dichloroethene have been measured with vibrational resolution at photon energies between 19 eV and 90 eV. Calculations of photoelectron anisotropy parameters, β, and harmo... Read More about Vibronic interaction in trans-dichloroethene studied by vibration- and angle-resolved photoelectron spectroscopy using 19–90 eV photon energy.

Selective Gas Uptake and Rotational Dynamics in a (3,24)-Connected Metal–Organic Framework Material (2021)
Journal Article
Trenholme, W. J., Kolokolov, D. I., Bound, M., Argent, S. P., Gould, J. A., Li, J., …Schröder, M. (2021). Selective Gas Uptake and Rotational Dynamics in a (3,24)-Connected Metal–Organic Framework Material. Journal of the American Chemical Society, 143(9), 3348–3358. https://doi.org/10.1021/jacs.0c11202

The desolvated (3,24)-connected metal-organic framework (MOF) material, MFM-160a, [Cu3(L)(H2O)3] [H6L = 1,3,5-triazine-2,4,6-tris(aminophenyl-4-isophthalic acid)] exhibits excellent high pressure uptake of CO2 (110 wt% at 20 bar, 298 K) and highly se... Read More about Selective Gas Uptake and Rotational Dynamics in a (3,24)-Connected Metal–Organic Framework Material.

Understanding charge transport in wavy 2D covalent organic frameworks (2021)
Journal Article
Martínez-Abadía, M., Strutyński, K., Stoppiello, C. T., Lerma Berlanga, B., Martí-Gastaldo, C., Khlobystov, A. N., …Mateo-Alonso, A. (2021). Understanding charge transport in wavy 2D covalent organic frameworks. Nanoscale, 13(14), 6829-6833. https://doi.org/10.1039/d0nr08962a

Understanding charge transport in 2D covalent organic frameworks is crucial to increase their performance. Herein a new wavy 2D covalent organic framework has been designed, synthesized and studied to shine light on the structural factors that domina... Read More about Understanding charge transport in wavy 2D covalent organic frameworks.