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Paramagnetic Probes for Magnetic Resonance (2013)
Thesis
Harvey, P. Paramagnetic Probes for Magnetic Resonance. (Thesis). Durham University. https://nottingham-repository.worktribe.com/output/2829768

Novel paramagnetic lanthanide complexes have been synthesised for use as probes for magnetic resonance imaging and spectroscopy. Initially, complexes containing a trifluoromethyl group were examined for 19F MRI/S, due to the large chemical shift rang... Read More about Paramagnetic Probes for Magnetic Resonance.

Experimental measurement and theoretical assessment of fast lanthanide electronic relaxation in solution with four series of isostructural complexes (2012)
Journal Article
Funk, A. M., Fries, P. H., Harvey, P., Kenwright, A. M., & Parker, D. (2012). Experimental measurement and theoretical assessment of fast lanthanide electronic relaxation in solution with four series of isostructural complexes. Journal of Physical Chemistry A, 117(5), 905-917. https://doi.org/10.1021/jp311273x

The rates of longitudinal relaxation for ligand nuclei in four isostructural series of lanthanide(III) complexes have been measured by solution state NMR at 295 K at five magnetic fields in the range 4.7-16.5 T. The electronic relaxation time Tle is... Read More about Experimental measurement and theoretical assessment of fast lanthanide electronic relaxation in solution with four series of isostructural complexes.

Paramagnetic 19F Chemical Shift Probes that Respond Selectively to Calcium or Citrate Levels and Signal Ester Hydrolysis (2012)
Journal Article
Harvey, P., Chalmers, K. H., De Luca, E., Mishra, A., & Parker, D. (2012). Paramagnetic 19F Chemical Shift Probes that Respond Selectively to Calcium or Citrate Levels and Signal Ester Hydrolysis. Chemistry - A European Journal, 18(28), 8748-8757. https://doi.org/10.1002/chem.201200737

Paramagnetic magnetic resonance chemical shift probes containing a proximal CF3 group have been characterised. Different systems have been created that report reversible changes in calcium ion concentrations in the millimolar regime, signal the prese... Read More about Paramagnetic 19F Chemical Shift Probes that Respond Selectively to Calcium or Citrate Levels and Signal Ester Hydrolysis.