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The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

Martin, Adam D.; Easun, Timothy L.; Argent, Stephen P.; Lewis, William; Blake, Alexander J.; Schr�der, Martin

The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene Thumbnail


Authors

MOHAMED ADAM MOHAMED.ADAM@NOTTINGHAM.AC.UK
Senior Research Fellow

Timothy L. Easun

William Lewis

Alexander J. Blake

Martin Schr�der



Abstract

Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

Citation

Martin, A. D., Easun, T. L., Argent, S. P., Lewis, W., Blake, A. J., & Schröder, M. (2016). The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene. CrystEngComm, 19(4), 603-607. https://doi.org/10.1039/c6ce01965j

Journal Article Type Article
Acceptance Date Oct 1, 2016
Online Publication Date Nov 16, 2016
Publication Date Nov 16, 2016
Deposit Date Nov 25, 2016
Publicly Available Date Nov 25, 2016
Journal CrystEngComm
Electronic ISSN 1466-8033
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 19
Issue 4
Pages 603-607
DOI https://doi.org/10.1039/c6ce01965j
Public URL https://nottingham-repository.worktribe.com/output/828280
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2017/CE/C6CE01965J#!divAbstract
Additional Information : This document is CrossCheck deposited; : Supplementary Information; : Crystal Structure Data; : William Lewis (ResearcherID); : Martin Schröder (ORCID); : The Royal Society of Chemistry has an exclusive publication licence for this journal; OPEN ACCESS: This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0); : Received 9 September 2016; Accepted 1 October 2016; Advance Article published 16 November 2016; Version of Record published 23 January 2017
Contract Date Nov 25, 2016

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