A Rechargeable High-Temperature Molten Salt Iron–Oxygen Battery

Peng, Cheng; Guan, Chengzhi; Lin, Jun; Zhang, Shiyu; Bao, Hongliang; Wang, Yu; Xiao, Guoping; Chen, George Zheng; Wang, Jian Qiang

Abstract

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The energy and power density of conventional batteries are far lower than their theoretical expectations, primarily because of slow reaction kinetics that are often observed under ambient conditions. Here we describe a low-cost and high-temperature rechargeable iron–oxygen battery containing a bi-phase electrolyte of molten carbonate and solid oxide. This new design merges the merits of a solid–oxide fuel cell and molten metal–air battery, offering significantly improved battery reaction kinetics and power capability without compromising the energy capacity. The as-fabricated battery prototype can be charged at high current density, and exhibits excellent stability and security in the highly charged state. It typically exhibits specific energy, specific power, energy density, and power density of 129.1 Wh kg−1, 2.8 kW kg−1, 388.1 Wh L−1, and 21.0 kW L−1, respectively, based on the mass and volume of the molten salt.

Citation

Peng, C., Guan, C., Lin, J., Zhang, S., Bao, H., Wang, Y., Xiao, G., Chen, G. Z., & Wang, J. Q. (2018). A Rechargeable High-Temperature Molten Salt Iron–Oxygen Battery. ChemSusChem, 11(11), 1880-1886. https://doi.org/10.1002/cssc.201800237

• Journal Article Type: Article
• Acceptance Date: Apr 17, 2018
• Online Publication Date: Apr 17, 2018
• Publication Date: Jun 11, 2018
• Deposit Date: Apr 24, 2018
• Publicly Available Date: Apr 18, 2019
• Journal: ChemSusChem
• Print ISSN: 1864-5631
• Electronic ISSN: 1864-564X
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 11
• Issue: 11
• Pages: 1880-1886
• DOI: https://doi.org/10.1002/cssc.201800237
• Keywords: high-temperature, rechargeable iron-oxygen battery, molten salt, yttria stabilized zirconia, electrochemical energy storage
• Public URL: https://nottingham-repository.worktribe.com/output/926268
• Publisher URL: https://onlinelibrary.wiley.com/doi/abs/10.1002/cssc.201800237
• Additional Information: This is the peer reviewed version of the following article: Peng, Cheng and Guan, Chengzhi and Lin, Jun and Zhang, Shiyu and Bao, Hongliang and Wang, Yu and Xiao, Guoping and Chen, George Zheng and Wang, Jianqiang (2018) A rechargeable high-temperature molten salt iron-oxygen battery. ChemSusChem . ISSN 1864-5631 , which has been published in final form athttps://onlinelibrary.wiley.com/doi/abs/10.1002/cssc.201800237. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving
• Contract Date: Apr 24, 2018