Perylene‐Grafted Silicas: Mechanistic Study and Applications in Heterogeneous Photoredox Catalysis

Carrillo, Adela I.; Elhage, Ayda; Marin, M. Luisa; Lanterna, Anabel E.

Abstract

A mechanistic study is herein presented for the use of heterogeneous photocatalysts based on perylene moieties. First, the successful immobilization of perylene diimides (PDI) on silica matrices is demonstrated, including their full characterization by means of electronic microscopy, surface area measurements, powder XRD, thermogravimetric analysis, and FTIR, 29Si and 13C solid‐state NMR, fluorescence, and diffuse reflectance spectroscopies. Then, the photoredox activity of the material was tested by using two model reactions, alkene oxidation and 4‐nitrobenzylbromide reduction, and mechanistic studies were performed. The mechanistic insights into their photoredox activity show they have promising dual photocatalytic activity for both organic oxidations and reductions.

Citation

Carrillo, A. I., Elhage, A., Marin, M. L., & Lanterna, A. E. (2019). Perylene‐Grafted Silicas: Mechanistic Study and Applications in Heterogeneous Photoredox Catalysis. Chemistry - A European Journal, 25(65), 14928-14934. https://doi.org/10.1002/chem.201903539

• Journal Article Type: Article
• Acceptance Date: Sep 18, 2019
• Online Publication Date: Oct 25, 2019
• Publication Date: Nov 22, 2019
• Deposit Date: Jun 22, 2020
• Publicly Available Date: Oct 26, 2020
• Journal: Chemistry – A European Journal
• Print ISSN: 0947-6539
• Electronic ISSN: 1521-3765
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 25
• Issue: 65
• Pages: 14928-14934
• DOI: https://doi.org/10.1002/chem.201903539
• Keywords: General Chemistry
• Public URL: https://nottingham-repository.worktribe.com/output/4442687
• Publisher URL: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201903539
• Additional Information: This is the peer reviewed version of the following article: A. I. Carrillo, A. Elhage, M. L. Marin, A. E. Lanterna, Chem. Eur. J. 2019 , 25 , 14928, which has been published in final form at https://doi.org/10.1002/chem.201903539. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.