A lithium-air battery and gas handling system demonstrator

Jordan, Jack W.; Vailaya, Ganesh; Holc, Conrad; Jenkins, Max; McNulty, Rory C.; Puscalau, Constantin; Tokay, Begum; Laybourn, Andrea; Gao, Xiangwen; Walsh, Darren A.; Newton, Graham N.; Bruce, Peter G.; Johnson, Lee R.

Abstract

The lithium-air (Li-air) battery offers one of the highest practical specific energy densities of any battery system at >400 W h kgsystem−1. The practical cell is expected to operate in air, which is flowed into the positive porous electrode where it forms Li2O2 on discharge and is released as O2 on charge. The presence of CO2 and H2O in the gas stream leads to the formation of oxidatively robust side products, Li2CO3 and LiOH, respectively. Thus, a gas handling system is needed to control the flow and remove CO2 and H2O from the gas supply. Here we present the first example of an integrated Li-air battery with in-line gas handling, that allows control over the flow and composition of the gas supplied to a Li-air cell and simultaneous evaluation of the cell and scrubber performance. Our findings reveal that O2 flow can drastically impact the capacity of cells and confirm the need for redox mediators. However, we show that current air-electrode designs translated from fuel cell technology are not suitable for Li-air cells as they result in the need for higher gas flow rates than required theoretically. This puts the scrubber under a high load and increases the requirements for solvent saturation and recapture. Our results clarify the challenges that must be addressed to realise a practical Li-air system and will provide vital insight for future modelling and cell development.

Citation

Jordan, J. W., Vailaya, G., Holc, C., Jenkins, M., McNulty, R. C., Puscalau, C., …Johnson, L. R. (2024). A lithium-air battery and gas handling system demonstrator. Faraday Discussions, 248, 381-391. https://doi.org/10.1039/d3fd00137g

• Journal Article Type: Article
• Acceptance Date: Jul 13, 2023
• Online Publication Date: Jul 18, 2023
• Publication Date: Jan 1, 2024
• Deposit Date: Sep 12, 2023
• Publicly Available Date: Sep 12, 2023
• Journal: Faraday Discussions
• Print ISSN: 1359-6640
• Electronic ISSN: 1364-5498
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 248
• Pages: 381-391
• DOI: https://doi.org/10.1039/d3fd00137g
• Keywords: Physical and Theoretical Chemistry
• Public URL: https://nottingham-repository.worktribe.com/output/25253424
• Publisher URL: https://pubs.rsc.org/en/content/articlelanding/2023/FD/D3FD00137G