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A lithium-air battery and gas handling system demonstrator

Jordan, Jack W.; Vailaya, Ganesh; Holc, Conrad; Jenkins, Max; McNulty, Rory C.; Puscalau, Constantin; Tokay, Begum; Laybourn, Andrea; Gao, Xiangwen; Walsh, Darren A.; Newton, Graham N.; Bruce, Peter G.; Johnson, Lee R.

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Authors

JACK JORDAN JACK.JORDAN2@NOTTINGHAM.AC.UK
Postdoctoral Research Assistant

Ganesh Vailaya

Conrad Holc

Max Jenkins

Rory C. McNulty

Constantin Puscalau

BEGUM PEISSEL BEGUM.TOKAY@NOTTINGHAM.AC.UK
Professor of Chemical Engineering

ANDREA LAYBOURN ANDREA.LAYBOURN@NOTTINGHAM.AC.UK
Assistant Professor in Chemical Engineering

Xiangwen Gao

DARREN WALSH DARREN.WALSH@NOTTINGHAM.AC.UK
Professor of Chemistry

Peter G. Bruce

LEE JOHNSON LEE.JOHNSON@NOTTINGHAM.AC.UK
Professor of Electrochemistry



Abstract

The lithium-air (Li-air) battery offers one of the highest practical specific energy densities of any battery system at >400 W h kgsystem−1. The practical cell is expected to operate in air, which is flowed into the positive porous electrode where it forms Li2O2 on discharge and is released as O2 on charge. The presence of CO2 and H2O in the gas stream leads to the formation of oxidatively robust side products, Li2CO3 and LiOH, respectively. Thus, a gas handling system is needed to control the flow and remove CO2 and H2O from the gas supply. Here we present the first example of an integrated Li-air battery with in-line gas handling, that allows control over the flow and composition of the gas supplied to a Li-air cell and simultaneous evaluation of the cell and scrubber performance. Our findings reveal that O2 flow can drastically impact the capacity of cells and confirm the need for redox mediators. However, we show that current air-electrode designs translated from fuel cell technology are not suitable for Li-air cells as they result in the need for higher gas flow rates than required theoretically. This puts the scrubber under a high load and increases the requirements for solvent saturation and recapture. Our results clarify the challenges that must be addressed to realise a practical Li-air system and will provide vital insight for future modelling and cell development.

Citation

Jordan, J. W., Vailaya, G., Holc, C., Jenkins, M., McNulty, R. C., Puscalau, C., …Johnson, L. R. (2024). A lithium-air battery and gas handling system demonstrator. Faraday Discussions, 248, 381-391. https://doi.org/10.1039/d3fd00137g

Journal Article Type Article
Acceptance Date Jul 13, 2023
Online Publication Date Jul 18, 2023
Publication Date Jan 1, 2024
Deposit Date Sep 12, 2023
Publicly Available Date Sep 12, 2023
Journal Faraday Discussions
Print ISSN 1359-6640
Electronic ISSN 1364-5498
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 248
Pages 381-391
DOI https://doi.org/10.1039/d3fd00137g
Keywords Physical and Theoretical Chemistry
Public URL https://nottingham-repository.worktribe.com/output/25253424
Publisher URL https://pubs.rsc.org/en/content/articlelanding/2023/FD/D3FD00137G

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