Polyvinyl chloride (PVC) derived microporous carbons prepared via hydrothermal dechlorination and potassium hydroxide activation for efficient CO2 capture

Yang, Fangming; Liu, Xin; Li, Mengbin; Uguna, Clement; Wang, Wenlong; Sun, Chenggong

Abstract

Hydrothermal dechlorination has been widely studied for recycling end-of-life polyvinyl chloride while the impact of embedded metal additives, a major component of many waste PVC products, has rarely been reported. In this study, hydrothermal treatment of used polyvinyl chloride pipe was carried out at a temperature range between 220 and 280 °C to understand the role of metal additives in the dechlorination process. The potential application of chlorine-free hydrochar as the precursor to prepare CO2 sorbents via chemical activation was also evaluated. The results demonstrated that the well-distributed calcium carbonate in the polyvinyl chloride matrix, acting as an in-situ neutralization agent, could accelerate the dechlorination of PVC, over 98.4% of chlorine was removed at 260 °C or higher. Using the hydrochar prepared at 260 °C as a single precursor, a series of activated carbons were successfully prepared via a facile chemical activation process. Those hydrochar-derived carbons have a microporous dominant structure with high surface area and total pore volume reaching up to 1927 m2 g−1 and 0.85 cm3 g−1, which showed great potential as CO2 sorbents. Tested at 25 °C, the microporous carbons exhibited both remarkable CO2 adsorption capacities of 1.60 mmol g−1 and 4.05 mmol g−1 at 100 kPa and high CO2/N2 selectivity of 42 at 15 kPa CO2. Advanced characterization demonstrated that the excellent CO2 adsorption performance originated from a unique combination of ultra-microporosity and surface chemistry. This work provides an effective and sustainable strategy to recycle hard-to-handle chlorinated plastic waste and reduce carbon emissions.

Citation

Yang, F., Liu, X., Li, M., Uguna, C., Wang, W., & Sun, C. (2023). Polyvinyl chloride (PVC) derived microporous carbons prepared via hydrothermal dechlorination and potassium hydroxide activation for efficient CO2 capture. Renewable and Sustainable Energy Reviews, 180, Article 113279. https://doi.org/10.1016/j.rser.2023.113279

• Journal Article Type: Article
• Acceptance Date: Mar 27, 2023
• Online Publication Date: Apr 29, 2023
• Publication Date: 2023-07
• Deposit Date: Aug 11, 2023
• Publicly Available Date: Apr 30, 2024
• Journal: Renewable and Sustainable Energy Reviews
• Print ISSN: 1364-0321
• Electronic ISSN: 1879-0690
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 180
• Article Number: 113279
• DOI: https://doi.org/10.1016/j.rser.2023.113279
• Keywords: Renewable Energy, Sustainability and the Environment
• Public URL: https://nottingham-repository.worktribe.com/output/20288057
• Publisher URL: https://www.sciencedirect.com/science/article/abs/pii/S1364032123001351?via%3Dihub
• Additional Information: This article is maintained by: Elsevier; Article Title: Polyvinyl chloride (PVC) derived microporous carbons prepared via hydrothermal dechlorination and potassium hydroxide activation for efficient CO2 capture; Journal Title: Renewable and Sustainable Energy Reviews; CrossRef DOI link to publisher maintained version: https://doi.org/10.1016/j.rser.2023.113279; Content Type: article; Copyright: © 2023 Elsevier Ltd. All rights reserved.