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Observation of the onset of torsion-induced, mode-specific dissipative intramolecular vibrational redistribution (IVR) (2019)
Journal Article
Kemp, D. J., Tuttle, W. D., Gardner, A. M., Whalley, L. E., & Wright, T. G. (2019). Observation of the onset of torsion-induced, mode-specific dissipative intramolecular vibrational redistribution (IVR). Journal of Chemical Physics, 151(6), Article 064308. https://doi.org/10.1063/1.5115329

Evidence is found showing that coupling with vibration-torsion (“vibtor”) levels of both in-plane and out-of-plane vibrations is instrumental in causing dissipative intramolecular vibrational redistribution (IVR). Both zero-electron-kinetic-energy (Z... Read More about Observation of the onset of torsion-induced, mode-specific dissipative intramolecular vibrational redistribution (IVR).

Complexity surrounding an apparently simple Fermi resonance in p-fluorotoluene revealed using two-dimensional laser-induced fluorescence (2D-LIF) spectroscopy (2019)
Journal Article
Kemp, D. J., Whalley, L. E., Gardner, A. M., Tuttle, W. D., Warner, L. G., & Wright, T. G. (2019). Complexity surrounding an apparently simple Fermi resonance in p-fluorotoluene revealed using two-dimensional laser-induced fluorescence (2D-LIF) spectroscopy. Journal of Chemical Physics, 150(6), 064306/1-064306/14. https://doi.org/10.1063/1.5083682

Two-dimensional laser-induced fluorescence (2D-LIF) spectroscopy is a powerful tool allowing overlapped features in an electronic spectrum to be separated, and interactions between vibrations and torsions to be identified. Here the technique is emplo... Read More about Complexity surrounding an apparently simple Fermi resonance in p-fluorotoluene revealed using two-dimensional laser-induced fluorescence (2D-LIF) spectroscopy.