All Outputs (2)

Metal–organic frameworks constructed from Group 1 metals (Li, Na) and silicon-centered linkers (2018)
Journal Article
Pugh, D., Ashworth, E., Robertson, K., Delmas, L. C., White, A. J. P., Horton, P. N., …Davies, R. P. (2019). Metal–organic frameworks constructed from Group 1 metals (Li, Na) and silicon-centered linkers. Crystal Growth and Design, 19(1), 487-497. https://doi.org/10.1021/acs.cgd.8b01567

A series of “light metal” metal–organic frameworks containing secondary building units (SBUs) based on Li+ and Na+ cations have been prepared using the silicon-centered linkers MexSi(p-C6H4CO2H)4-x (x = 2, 1, 0). The unipositive charge, small size, a... Read More about Metal–organic frameworks constructed from Group 1 metals (Li, Na) and silicon-centered linkers.

Integrated plug flow synthesis and crystallisation of pyrazinamide (2018)
Journal Article
Scott, C. D., Labes, R., Depardieu, M., Battilocchio, C., Davidson, M. G., Ley, S. V., …Robertson, K. (2018). Integrated plug flow synthesis and crystallisation of pyrazinamide. Reaction Chemistry and Engineering, 3(5), 631-634. https://doi.org/10.1039/c8re00087e

We report the integration of flow chemistry with plug flow crystallisation. Catalytic flow hydration of pyrazinecarbonitrile to pyrazinamide was performed in a packed bed column of MnO2. The effluent of this flow reactor was directly linked to a tri-... Read More about Integrated plug flow synthesis and crystallisation of pyrazinamide.