All Outputs (5)

A Simple Approach to the Visible-Light Photoactivation of Molecular Metal Oxides (2017)
Journal Article
Fujimoto, S., Cameron, J. M., Wei, R. J., Kastner, K., Robinson, D., Sans, V., …Oshio, H. (2017). A Simple Approach to the Visible-Light Photoactivation of Molecular Metal Oxides. Inorganic Chemistry, 56(20), 12169-12177. https://doi.org/10.1021/acs.inorgchem.7b01499

© 2017 American Chemical Society. This study explores a new method to maximize the visible-light-driven photocatalytic performance of organic-inorganic hybrid polyoxometalates (POMs). Experimental and theoretical investigations of a family of phospho... Read More about A Simple Approach to the Visible-Light Photoactivation of Molecular Metal Oxides.

Synthesis, crystal structures and magnetic properties of composites incorporating an Fe(II) spin crossover complex and polyoxometalates (2017)
Journal Article
Kuramochi, S., Shiga, T., Cameron, J. M., Newton, G. N., & Oshio, H. (2017). Synthesis, crystal structures and magnetic properties of composites incorporating an Fe(II) spin crossover complex and polyoxometalates. Inorganics, 5(3), Article 48. https://doi.org/10.3390/inorganics5030048

[Fe(dppOH)2]2+ (dppOH = 2,6-di(pyrazol-1-yl)-4-(hydroxymethyl)pyridine) is known to show spin crossover (SCO) behavior and light-induced excited spin state transitions (LIESST). Here, we show that the SCO properties of the [Fe(dppOH)2]2+ complex can... Read More about Synthesis, crystal structures and magnetic properties of composites incorporating an Fe(II) spin crossover complex and polyoxometalates.

An antiferromagnetically coupled heterometal Cu6Fe wheel (2017)
Journal Article
Saiki, R., Yoshida, N., Hoshino, N., Newton, G. N., Shiga, T., & Oshio, H. (2017). An antiferromagnetically coupled heterometal Cu6Fe wheel. Chemistry Letters, 46(8), https://doi.org/10.1246/cl.170365

A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6- (OH)2(OCH3)4](NO3)3¢6H2O (1¢6H2O) (H2L = 1-(2-pyridine) 3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals t... Read More about An antiferromagnetically coupled heterometal Cu6Fe wheel.

Redox-active organic-inorganic hybrid polyoxometalate micelles (2017)
Journal Article
Kastner, K., Kibler, A. J., Karjalainen, E., Fernandes, J. A., Sans, V., & Newton, G. (in press). Redox-active organic-inorganic hybrid polyoxometalate micelles. Journal of Materials Chemistry A, 5, https://doi.org/10.1039/C7TA00408G

A redox-active hybrid organic-inorganic polyoxometalate surfactant showed solvent-dependent self-assembly to form nano-scale architectures. The supramolecular assemblies exhibited contrasting electronic structure and redox activity to their molecular... Read More about Redox-active organic-inorganic hybrid polyoxometalate micelles.

A multi-redox responsive cyanometalate-based metallogel (2017)
Journal Article
Mitsumoto, K., Cameron, J., Wei, R. J., Nishikawa, H., Shiga, T., Nihei, M., …Oshio, H. (2017). A multi-redox responsive cyanometalate-based metallogel. Chemistry - A European Journal, 23(7), 1502-1506. https://doi.org/10.1002/chem.201605542

A tetrathiafulvalene (TTF) based tridentate ligand (-(4’-methyl-4,5-di-n-dodecylthylthiotetrathiafulvalene-5’-ylthio)-’-[tris-2,2,2-(1-pyrazolyl)ethoxy]-p-xylene) (L) with long-chain alkyl moieties was prepared in order to obtain a new multi-redox... Read More about A multi-redox responsive cyanometalate-based metallogel.