All Outputs (4)

Orbital engineering: photoactivation of an organofunctionalized polyoxotungstate (2016)
Journal Article
Newton, G., Oshio, H., Cameron, J., Fujimoto, S., Kastner, K., Wei, R. J., …Sans, V. (2017). Orbital engineering: photoactivation of an organofunctionalized polyoxotungstate. Chemistry - A European Journal, 23(1), 47-50. https://doi.org/10.1002/chem.201605021

Tungsten-based polyoxometalates (POMs) are employed as UV-driven photo-catalysts for a range of organic transformations. Their photoactivity is dependent on electronic transitions between frontier orbitals, and thus manipulation of orbital energy lev... Read More about Orbital engineering: photoactivation of an organofunctionalized polyoxotungstate.

Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex (2016)
Journal Article
Wei, R. J., Nakahara, R., Cameron, J. M., Newton, G., Shiga, T., Sagayama, H., …Oshio, H. (2016). Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex. Dalton Transactions, 45(43), 17104-17107. https://doi.org/10.1039/C6DT03416K

A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.

Oxalate-bridged heterometallic chains with monocationic dabco derivatives (2016)
Journal Article
Sakurai, T., Saiki, R., Wei, R. J., Newton, G., Shiga, T., & Oshio, H. (in press). Oxalate-bridged heterometallic chains with monocationic dabco derivatives. Dalton Transactions, 45, https://doi.org/10.1039/C6DT02955H

A series of bimetallic oxalate-bridged one-dimensional chains with monocationic dabco derivatives, ({R-dabco}[M(solv)2][Cr(ox)3]·n(solv)) (dabco = 1,4-diazabicyclo[2.2.2]octane, H2ox = oxalate; R = H, M = Co (1); R = H, M = Zn (2); R = Bu, M = Co (3)... Read More about Oxalate-bridged heterometallic chains with monocationic dabco derivatives.

Studies on the magnetic ground state of a spin Möbius strip (2016)
Journal Article
Newton, G., Hoshino, N., Matsumoto, T., Shiga, T., Nakano, M., Nojiri, H., …Oshio, H. (2016). Studies on the magnetic ground state of a spin Möbius strip. Chemistry - A European Journal, 22(40), 14205-14212. https://doi.org/10.1002/chem.201602439

Here we report the synthesis, structure and detailed characterisation of three n-membered oxovanadium rings, Nan[(V=O)nNan(H2O)n(α, β, or γ-CD)2]⋅mH2O (n = 6, 7, or 8), prepared by the reactions of (V=O)SO4⋅xH2O with α, β, or γ-cyclodextrins(CDs) and... Read More about Studies on the magnetic ground state of a spin Möbius strip.