All Outputs (5)

Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex (2015)
Journal Article
Gardner, B. M., Balázs, G., Scheer, M., Wooles, A. J., Tuna, F., McInnes, E. J., …Liddle, S. T. (2015). Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex. Angewandte Chemie International Edition, 54(50), 15250-15254. https://doi.org/10.1002/anie.201508600

The HAsAsH molecule has hitherto only been proposed tentatively as a short-lived species generated in electrochemical or microwave-plasma experiments. After two centuries of inconclusive or disproven claims of HAsAsH formation in the condensed phase,... Read More about Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex.

A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases (2015)
Journal Article
Perotto, C. U., Marshall, G., Jones, G. J., Lewis, W., McMaster, J., & Schröder, M. (2015). A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases. Chemical Communications, 51, https://doi.org/10.1039/c5cc05881c

Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configurat... Read More about A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases.

Synthesis and characterisation of halide, separated ion pair, and hydride cyclopentadienyl iron bis(diphenylphosphino)ethane derivatives (2015)
Journal Article
Patel, D., Wooles, A., Cornish, A. D., Steven, L., Davies, E. S., Evans, D. J., …Liddle, S. T. (2015). Synthesis and characterisation of halide, separated ion pair, and hydride cyclopentadienyl iron bis(diphenylphosphino)ethane derivatives. Dalton Transactions, 44(31), 14159-14177. https://doi.org/10.1039/c5dt00704f

Triamidoamine uranium(IV)-arsenic complexes containing one-, two-, and three-fold U-As bonding interactions (2015)
Journal Article
Gardner, B., Balázs, G., Scheer, M., Tuna, F., McInnes, E., McMaster, J., …Liddle, S. (2015). Triamidoamine uranium(IV)-arsenic complexes containing one-, two-, and three-fold U-As bonding interactions. Nature Chemistry, 7, Article 582. https://doi.org/10.1038/NCHEM.2279

An Inverted-Sandwich Diuranium ?-?5:?5-Cyclo-P5 Complex Supported by U-P5 ?-Bonding (2015)
Journal Article
Gardner, B. M., Tuna, F., McInnes, E. J., McMaster, J., Lewis, W., Blake, A. J., & Liddle, S. T. (2015). An Inverted-Sandwich Diuranium ?-?5:?5-Cyclo-P5 Complex Supported by U-P5 ?-Bonding. Angewandte Chemie International Edition, 54(24), 7068-7072. https://doi.org/10.1002/anie.201501728

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Abstract Reaction of [U(TrenTIPS)] [1, TrenTIPS=N(CH2CH2NSiiPr3)3] with 0.25 equivalents of P4 reproducibly affords the unprecedented actinide inverted sandwich cyclo-P5 complex [{U(TrenTIPS)}2(μ-η... Read More about An Inverted-Sandwich Diuranium ?-?5:?5-Cyclo-P5 Complex Supported by U-P5 ?-Bonding.