A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases
(2015)
Journal Article
Perotto, C. U., Marshall, G., Jones, G. J., Lewis, W., McMaster, J., & Schröder, M. (2015). A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases. Chemical Communications, 51, https://doi.org/10.1039/c5cc05881c
Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configurat... Read More about A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases.