All Outputs (3)

Cyanide-Bridged Decanuclear Cobalt–Iron Cage (2014)
Journal Article
Oshio, H., Shiga, T., Newton, G. N., Tetsuka, T., Nihei, M., Sakai, K., & Sekine, Y. (2014). Cyanide-Bridged Decanuclear Cobalt–Iron Cage. Inorganic Chemistry, 53(12), 5899-5901. https://doi.org/10.1021/ic500964m

A cyanide-bridged decanuclear [Co6Fe4] cluster was synthesized by a one-pot reaction, and the magnetic properties and electronic configuration were investigated. The complex displayed thermally controlled electron-transfer-coupled spin transition (ET... Read More about Cyanide-Bridged Decanuclear Cobalt–Iron Cage.

Programmable spin-state switching in a mixed-valence spin-crossover iron grid (2014)
Journal Article
Matsumoto, T., Newton, G. N., Shiga, T., Hayami, S., Matsui, Y., Okamoto, H., …Oshio, H. (2014). Programmable spin-state switching in a mixed-valence spin-crossover iron grid. Nature Communications, 5, 1-8. https://doi.org/10.1038/ncomms4865

Photo-switchable systems, such as discrete spin-crossover complexes and bulk iron–cobalt Prussian blue analogues, exhibit, at a given temperature, a bistability between low- and high-spin states, allowing the storage of binary data. Grouping differen... Read More about Programmable spin-state switching in a mixed-valence spin-crossover iron grid.

Lability-Controlled Syntheses of Heterometallic Clusters (2014)
Journal Article
Newton, G. N., Mitsumoto, K., Wei, R., Iijima, F., Shiga, T., Nishikawa, H., & Oshio, H. (2014). Lability-Controlled Syntheses of Heterometallic Clusters. Angewandte Chemie International Edition, 53(11), 2941-2944. doi:10.1002/anie.201309374