Negative area compressibility in silver(i) tricyanomethanide
(2013)
Journal Article
Hodgson, S. A., Adamson, J., Hunt, S. J., Cliffe, M. J., Cairns, A. B., Thompson, A. L., …Goodwin, A. L. (2014). Negative area compressibility in silver(i) tricyanomethanide. Chemical Communications, 2014(40), 5264-5266. https://doi.org/10.1039/c3cc47032f
The metal–organic framework copper(I) tricyanomethanide, Cu(tcm), undergoes a ferroelastic transition on cooling below Tf = 240 K. Thermal expansion measurements reveal an order-of-magnitude variation in framework flexibility across Tf. The low-tempe... Read More about Negative area compressibility in silver(i) tricyanomethanide.