Gold-catalyzed oxidative coupling of arylsilanes and arenes: Origin of selectivity and improved precatalyst
(2013)
Journal Article
Lloyd-Jones, G. C., Ball, L., & Russell, C. A. (2014). Gold-catalyzed oxidative coupling of arylsilanes and arenes: Origin of selectivity and improved precatalyst. Journal of the American Chemical Society, 136(1), 254-264. https://doi.org/10.1021/ja408712e
The mechanism of gold-catalyzed coupling of arenes with aryltrimethylsilanes has been investigated, employing an improved precatalyst (thtAuBr3) to facilitate kinetic analysis. In combination with linear free-energy relationships, kinetic isotope eff... Read More about Gold-catalyzed oxidative coupling of arylsilanes and arenes: Origin of selectivity and improved precatalyst.