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Atomic mechanism of metal crystal nucleus formation in a single-walled carbon nanotube (2020)
Journal Article
Cao, K., Biskupek, J., Stoppiello, C. T., McSweeney, R. L., Chamberlain, T. W., Liu, Z., …Kaiser, U. (2020). Atomic mechanism of metal crystal nucleus formation in a single-walled carbon nanotube. Nature Chemistry, 12, 921–928. https://doi.org/10.1038/s41557-020-0538-9

Knowing how crystals nucleate at the atomic scale is crucial for understanding, and in turn controlling, the structure and properties of a wide variety of materials. However, because of the scale and highly dynamic nature of nuclei, the formation and... Read More about Atomic mechanism of metal crystal nucleus formation in a single-walled carbon nanotube.

Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes (2019)
Journal Article
Jordan, J. W., Lowe, G. A., McSweeney, R. L., Stoppiello, C. T., Lodge, R. W., Skowron, S. T., …Khlobystov, A. N. (2019). Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes. Advanced Materials, 31(41), Article 1904182. https://doi.org/10.1002/adma.201904182

The development of next‐generation molecular‐electronic, electrocatalytic, and energy‐storage systems depends on the availability of robust materials in which molecular charge‐storage sites and conductive hosts are in intimate contact. It is shown he... Read More about Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes.

Comparison of atomic scale dynamics for the middle and late transition metal nanocatalysts (2018)
Journal Article
Cao, K., Zoberbier, T., Biskupek, J., Botos, A., McSweeney, R. L., Kurtoglu, A., …Khlobystov, A. N. (2018). Comparison of atomic scale dynamics for the middle and late transition metal nanocatalysts. Nature Communications, 9, 1-10. https://doi.org/10.1038/s41467-018-05831-z

Catalysis of chemical reactions by nanosized clusters of transition metals holds the key to the provision of sustainable energy and materials. However, the atomistic behaviour of nanocatalysts still remains largely unknown due to uncertainties associ... Read More about Comparison of atomic scale dynamics for the middle and late transition metal nanocatalysts.

Enhanced ‘in situ’ catalysis via microwave selective heating: catalytic chain transfer polymerisation (2014)
Journal Article
Adlington, K., McSweeney, R., Dimitrakis, G., Kingman, S. W., Robinson, J. P., & Irvine, D. J. (2014). Enhanced ‘in situ’ catalysis via microwave selective heating: catalytic chain transfer polymerisation. RSC Advances, 4(31), 16172-16180. https://doi.org/10.1039/c4ra00907j

An extremely facile, single stage, ‘in-situ’, Catalytic Chain Transfer Polymerisation (CCTP) process has been identified, where the optimal polymerisation process was shown to depend upon a combination of catalyst characteristics (i.e. solubility, se... Read More about Enhanced ‘in situ’ catalysis via microwave selective heating: catalytic chain transfer polymerisation.