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An in situ exploration of subsurface defect migration to a liquid water?exposed rutile TiO2(110) surface by XPS (2020)
Journal Article
Ahmed, M. H. M., Temperton, R. H., & O'Shea, J. N. (2021). An in situ exploration of subsurface defect migration to a liquid water?exposed rutile TiO2(110) surface by XPS. Surface and Interface Analysis, 53(12), 1013-1019. https://doi.org/10.1002/sia.6906

The ability of titanium dioixide to split water into OH? and H+ species is heavily dependent on the behaviour of defects in the crystal structure at or near the surface. We present an in situ study of defect migration in rutile TiO2(110) conducted us... Read More about An in situ exploration of subsurface defect migration to a liquid water?exposed rutile TiO2(110) surface by XPS.

Site-Selective Orbital Interactions in an Ultrathin Iron-Carbene Photosensitizer Film (2020)
Journal Article
Temperton, R. H., Rosemann, N. W., Guo, M., Johansson, N., Fredin, L. A., Prakash, O., …Persson, P. (2020). Site-Selective Orbital Interactions in an Ultrathin Iron-Carbene Photosensitizer Film. Journal of Physical Chemistry A, 124(8), 1603-1609. https://doi.org/10.1021/acs.jpca.0c00803

We present the first experimental study of the frontier orbitals in an ultrathin film of the novel hexa-carbene photosensitizer [Fe(btz)3]3+, where btz is 3,3′-dimethyl-1,1′-bis(p-tolyl)-4,4′-bis(1,2,3-triazol-5-ylidene). Resonant photoelectron spect... Read More about Site-Selective Orbital Interactions in an Ultrathin Iron-Carbene Photosensitizer Film.

Resonant inelastic X-ray scattering of a Ru photosensitizer: Insights from individual ligands to the electronic structure of the complete molecule (2019)
Journal Article
Temperton, R. H., Skowron, S. T., Handrup, K., Gibson, A. J., Nicolaou, A., Jaouen, N., …O’Shea, J. N. (2019). Resonant inelastic X-ray scattering of a Ru photosensitizer: Insights from individual ligands to the electronic structure of the complete molecule. Journal of Chemical Physics, 151(7), 1-9. https://doi.org/10.1063/1.5114692

N 1s Resonant Inelastic X-ray Scattering (RIXS) was used to probe the molecular electronic structure of the ruthenium photosensitizer complex cis-bis(isothiocyanato) bis(2,2′-bipyridyl-4,4′-dicarboxylato) ruthenium(II), known as “N3.” In order to int... Read More about Resonant inelastic X-ray scattering of a Ru photosensitizer: Insights from individual ligands to the electronic structure of the complete molecule.

Ultra-fast intramolecular vibronic coupling revealed by RIXS and RPES maps of an aromatic adsorbate on TiO2(110) (2018)
Journal Article
O'Shea, J. N., Handrup, K., Temperton, R. H., Gibson, A. J., Nicolaou, A., Jaouen, N., …Schnadt, J. (2018). Ultra-fast intramolecular vibronic coupling revealed by RIXS and RPES maps of an aromatic adsorbate on TiO2(110). Journal of Chemical Physics, 148(20), Article 204705. https://doi.org/10.1063/1.5024862

Two-dimensional resonant inelastic x-ray scattering (RIXS) and resonant photoelectron spectroscopy (RPES) maps are presented for multilayer and monolayer coverages of an aromatic molecule (bi-isonicotinic acid) on the rutile TiO2(110) single crystal... Read More about Ultra-fast intramolecular vibronic coupling revealed by RIXS and RPES maps of an aromatic adsorbate on TiO2(110).

On the suitability of high vacuum electrospray deposition for the fabrication of molecular electronic devices (2017)
Journal Article
Temperton, R. H., O'Shea, J. N., & Scurr, D. J. (2017). On the suitability of high vacuum electrospray deposition for the fabrication of molecular electronic devices. Chemical Physics Letters, 682, 15-19. https://doi.org/10.1016/j.cplett.2017.05.068

© 2017 We present a series of three studies investigating the potential application of high vacuum electrospray deposition to construct molecular electronic devices. Through the use of time of flight secondary ion mass spectrometry we explore the use... Read More about On the suitability of high vacuum electrospray deposition for the fabrication of molecular electronic devices.

Resonant core spectroscopies of the charge transfer interactions between C60 and the surfaces of Au(111), Ag(111), Cu(111) and Pt(111) (2016)
Journal Article
Gibson, A. J., Temperton, R. H., O'Shea, J. N., & Handrup, K. (2017). Resonant core spectroscopies of the charge transfer interactions between C60 and the surfaces of Au(111), Ag(111), Cu(111) and Pt(111). Surface Science, 657, https://doi.org/10.1016/j.susc.2016.11.009

Charge transfer interactions between C60 and the metal surfaces of Ag(111), Cu(111), Au(111) and Pt(111) have been studied using synchrotron-based photoemission, resonant photoemission and X-ray absorption spectroscopies. By placing the X-ray absorp... Read More about Resonant core spectroscopies of the charge transfer interactions between C60 and the surfaces of Au(111), Ag(111), Cu(111) and Pt(111).