All Outputs (3)

Measurement of proton tunneling in short hydrogen bonds in single crystals of 3,5 pyridinedicarboxylic acid using nuclear magnetic resonance spectroscopy (2014)
Journal Article
Frantsuzov, I., Ford, S. J., Radosavljevic-Evans, I., Horsewill, A. J., Trommsdorff, H. P., & Johnson, M. R. (2014). Measurement of proton tunneling in short hydrogen bonds in single crystals of 3,5 pyridinedicarboxylic acid using nuclear magnetic resonance spectroscopy. Physical Review Letters, 113, https://doi.org/10.1103/PhysRevLett.113.018301

In this letter, we present NMR spin-lattice and relaxometry data for proton transfer in one of the shortest known N-H???O hydrogen bonds in a single crystal of 3,5 pyridinedicarboxylic acid (35PDCA). It is widely believed that proton transfer by quan... Read More about Measurement of proton tunneling in short hydrogen bonds in single crystals of 3,5 pyridinedicarboxylic acid using nuclear magnetic resonance spectroscopy.

Symmetry-breaking in the endofullerene H2O@C60 revealed in the quantum dynamics of ortho and para-water: a neutron scattering investigation (2014)
Journal Article
Goh, K. S., Jimenez-Ruiz, M., Johnson, M. R., Rols, S., Ollivier, J., Denning, M. S., …Horsewill, A. J. (2014). Symmetry-breaking in the endofullerene H2O@C60 revealed in the quantum dynamics of ortho and para-water: a neutron scattering investigation. Physical Chemistry Chemical Physics, 16(39), https://doi.org/10.1039/c4cp03272a

Inelastic neutron scattering (INS) has been employed to investigate the quantum dynamics of water molecules permanently entrapped inside the cages of C60 fullerene molecules. This study of the supramolecular complex, H2O@C60, provides the unique oppo... Read More about Symmetry-breaking in the endofullerene H2O@C60 revealed in the quantum dynamics of ortho and para-water: a neutron scattering investigation.

Confirming a predicted selection rule in inelastic neutron scattering spectroscopy: the quantum translator-rotator H2 entrapped inside C60 (2014)
Journal Article
Xu, M., Jiménez-Ruiz, M., Johnson, M. R., Rols, S., Ye, S., Carravetta, M., …Horsewill, A. J. (2014). Confirming a predicted selection rule in inelastic neutron scattering spectroscopy: the quantum translator-rotator H2 entrapped inside C60. Physical Review Letters, 113(123001), https://doi.org/10.1103/PhysRevLett.113.123001

We report an inelastic neutron scattering (INS) study of H2 molecule encapsulated inside the fullerene C60 which confirms the recently predicted selection rule, the first to be established for the INS spectroscopy of aperiodic, discrete molecular com... Read More about Confirming a predicted selection rule in inelastic neutron scattering spectroscopy: the quantum translator-rotator H2 entrapped inside C60.