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Nucleophilic Fluorination Catalyzed by a Cyclometallated Rhodium Complex (2022)
Journal Article
Morgan, P. J., Saunders, G. C., Macgregor, S. A., Marr, A. C., & Licence, P. (2022). Nucleophilic Fluorination Catalyzed by a Cyclometallated Rhodium Complex. Organometallics, 41(7), 883–891. https://doi.org/10.1021/acs.organomet.2c00052

Quantitative catalytic nucleophilic fluorination of a range of acyl chlorides to acyl fluorides was promoted by a cyclometallated rhodium complex [(η5,κ2C-C5Me4CH2C6F5CH2NC3H2NMe)- RhCl] (1). 1 can be prepared in high yields from commercially availab... Read More about Nucleophilic Fluorination Catalyzed by a Cyclometallated Rhodium Complex.