All Outputs (2)

Glass formation via structural fragmentation of a 2D coordination network (2015)
Journal Article
Umeyama, D., Funnell, N. P., Cliffe, M. J., Hill, J. A., Goodwin, A. L., Hijikata, Y., …Kitagawa, S. (2015). Glass formation via structural fragmentation of a 2D coordination network. Chemical Communications, 51(64), 12728-12731. https://doi.org/10.1039/c5cc04626b

The structure of a glass obtained by the melt quenching of a two-dimensional (2D) coordination network was examined. X-ray analyses disclosed a 2D-to-0D structural transformation before and after glass formation. The mechanism is unique to coordinati... Read More about Glass formation via structural fragmentation of a 2D coordination network.

Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal–organic framework (2015)
Journal Article
Cliffe, M. J., Hill, J. A., Murray, C. A., Coudert, F., & Goodwin, A. L. (2015). Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal–organic framework. Physical Chemistry Chemical Physics, 17(17), 11586-11592. https://doi.org/10.1039/c5cp01307k

Thermally-densified hafnium terephthalate UiO-66(Hf) is shown to exhibit the strongest isotropic negative thermal expansion (NTE) effect yet reported for a metal–organic framework (MOF). Incorporation of correlated vacancy defects within the framewor... Read More about Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal–organic framework.