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Orbital engineering: photoactivation of an organofunctionalized polyoxotungstate (2016)
Journal Article
Newton, G., Oshio, H., Cameron, J., Fujimoto, S., Kastner, K., Wei, R. J., …Sans, V. (2017). Orbital engineering: photoactivation of an organofunctionalized polyoxotungstate. Chemistry - A European Journal, 23(1), 47-50. https://doi.org/10.1002/chem.201605021

Tungsten-based polyoxometalates (POMs) are employed as UV-driven photo-catalysts for a range of organic transformations. Their photoactivity is dependent on electronic transitions between frontier orbitals, and thus manipulation of orbital energy lev... Read More about Orbital engineering: photoactivation of an organofunctionalized polyoxotungstate.

Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex (2016)
Journal Article
Wei, R. J., Nakahara, R., Cameron, J. M., Newton, G., Shiga, T., Sagayama, H., …Oshio, H. (2016). Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex. Dalton Transactions, 45(43), 17104-17107. https://doi.org/10.1039/C6DT03416K

A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.