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On the real catalytically active species for CO2 fixation into cyclic carbonates under near ambient conditions: dissociation equilibrium of [BMIm][Fe(NO)2Cl2] dependant on reaction temperature (2018)
Journal Article
Leu, M. K., Vicente, I., Fernandes, J. A., de Pedro, I., Dupont, J., Sans, V., …Cano, I. (2019). On the real catalytically active species for CO2 fixation into cyclic carbonates under near ambient conditions: dissociation equilibrium of [BMIm][Fe(NO)2Cl2] dependant on reaction temperature. Applied Catalysis B: Environmental, 245, 240-250. https://doi.org/10.1016/j.apcatb.2018.12.062

An imidazolium based iron-containing ionic liquid [BMIm][Fe(NO)2Cl2] (BMIm = 1-n-butyl-3-methyl-imidazolium) has been synthesized for the first time and fully characterized employing a wide range of techniques. The iron-based containing ionic liquid... Read More about On the real catalytically active species for CO2 fixation into cyclic carbonates under near ambient conditions: dissociation equilibrium of [BMIm][Fe(NO)2Cl2] dependant on reaction temperature.

Supramolecular interaction of non-racemic benzimidazolium based ion pairs with chiral substrates (2018)
Journal Article
Mumtaz, S., Cano, I., Mumtaz, N., Abbas, A., Dupont, J., & Gondal, H. Y. (2018). Supramolecular interaction of non-racemic benzimidazolium based ion pairs with chiral substrates. Physical Chemistry Chemical Physics, 20(32), 20821-20826. https://doi.org/10.1039/C8CP03881C

A series of novel benzimidazolium-based non-racemic ionic liquids (ILs) was synthesized from low–cost chiral terpenoid alcohols and fully characterized by the use of a wide variety of techniques, such as DSC, ESI-MS, ATR FT-IR, polarimetry as well as... Read More about Supramolecular interaction of non-racemic benzimidazolium based ion pairs with chiral substrates.

Tuneable ionic control of polymeric films for inkjet based 3D printing (2018)
Journal Article
Karjalainen, E., Wales, D. J., Gunasekera, D. H., Dupont, J., Licence, P., Wildman, R. D., & Sans, V. (in press). Tuneable ionic control of polymeric films for inkjet based 3D printing. ACS Sustainable Chemistry and Engineering, https://doi.org/10.1021/acssuschemeng.7b04279

Inkjet printing is a powerful additive manufacturing (AM) technique to generate advanced and complex geometries. However, requirements of low viscosity and surface tension are limiting the range of functional inks available, thus hindering the develo... Read More about Tuneable ionic control of polymeric films for inkjet based 3D printing.

Selective Carbon Dioxide Hydrogenation Driven by Ferromagnetic RuFe Nanoparticles in Ionic Liquids (2018)
Journal Article
Qadir, M. I., Weilhard, A., Fernandes, J. A., de Pedro, I., Vieira, B. J. C., Waerenborgh, J. C., & Dupont, J. (2018). Selective Carbon Dioxide Hydrogenation Driven by Ferromagnetic RuFe Nanoparticles in Ionic Liquids. ACS Catalysis, 8(2), 1621-1627. https://doi.org/10.1021/acscatal.7b03804

© 2018 American Chemical Society. CO2 is selectively hydrogenated to HCO2H or hydrocarbons (HCs) by RuFe nanoparticles (NPs) in ionic liquids (ILs) under mild reaction conditions. The generation of HCO2H occurs in ILs containing basic anions, whereas... Read More about Selective Carbon Dioxide Hydrogenation Driven by Ferromagnetic RuFe Nanoparticles in Ionic Liquids.

Selective CO2 hydrogenation to formic acid with multifunctional ionic liquids (2018)
Journal Article
Weilhard, A., Qadir, M. I., Sans, V., & Dupont, J. (in press). Selective CO2 hydrogenation to formic acid with multifunctional ionic liquids. ACS Catalysis, 8, https://doi.org/10.1021/acscatal.7b03931

The development of simple, cost-effective and sustainable methods to transform CO2 into feedstock chemicals is essential to reduce the dependence on fossil fuels of the chemical industry. Here, we report the selective and efficient catalytic hydrogen... Read More about Selective CO2 hydrogenation to formic acid with multifunctional ionic liquids.