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All Outputs (5)

In situ Crosslinking of Nanostructured Block Copolymer Microparticles in Supercritical Carbon Dioxide (2019)
Journal Article
He, G., Bennett, T. M., Alias, K., Jiang, L., Schwab, S., Alauhdin, M., & Howdle, S. M. (2019). In situ Crosslinking of Nanostructured Block Copolymer Microparticles in Supercritical Carbon Dioxide. Polymer Chemistry, 10(29), 3960-3972. https://doi.org/10.1039/c9py00556k

We report a novel and facile approach to “fix” the internal nanostructure of block copolymer (BCP) microparticles via in situ crosslinking copolymerisation in dispersion in supercritical CO2 (scCO2). By delaying the addition of the crosslinker and a... Read More about In situ Crosslinking of Nanostructured Block Copolymer Microparticles in Supercritical Carbon Dioxide.

Monitoring morphology evolution within block copolymer microparticles during dispersion polymerisation in supercritical carbon dioxide: a high pressure SAXS study (2019)
Journal Article
Alauhdin, M., Bennett, T. M., He, G., Bassett, S. P., Portale, G., Bras, W., …Howdle, S. M. (2019). Monitoring morphology evolution within block copolymer microparticles during dispersion polymerisation in supercritical carbon dioxide: a high pressure SAXS study. Polymer Chemistry, 10(7), 860-871. https://doi.org/10.1039/c8py01578c

Reversible addition–fragmentation chain transfer (RAFT) dispersion polymerisation in supercritical carbon dioxide is an effective process for creating block copolymer microparticles with internal nanostructures. Here we report an alternative synthesi... Read More about Monitoring morphology evolution within block copolymer microparticles during dispersion polymerisation in supercritical carbon dioxide: a high pressure SAXS study.

Clean Block Copolymer Microparticles from Supercritical CO 2 : Universal Templates for the Facile and Scalable Fabrication of Hierarchical Mesostructured Metal Oxides (2018)
Journal Article
Bennett, T. M., He, G., Larder, R. R., Fischer, M. G., Rance, G. A., Fay, M. W., …Howdle, S. M. (2018). Clean Block Copolymer Microparticles from Supercritical CO 2 : Universal Templates for the Facile and Scalable Fabrication of Hierarchical Mesostructured Metal Oxides. Nano Letters, 18(12), 7560-7569. https://doi.org/10.1021/acs.nanolett.8b03044

© 2018 American Chemical Society. Metal oxide microparticles with well-defined internal mesostructures are promising materials for a variety of different applications, but practical routes to such materials that allow the constituent structural leng... Read More about Clean Block Copolymer Microparticles from Supercritical CO 2 : Universal Templates for the Facile and Scalable Fabrication of Hierarchical Mesostructured Metal Oxides.

A facile route to bespoke macro- and mesoporous block copolymer microparticles (2018)
Journal Article
He, G., Bennett, T. M., Alauhdin, M., Fay, M. W., Liu, X., Schwab, S. T., …Howdle, S. M. (in press). A facile route to bespoke macro- and mesoporous block copolymer microparticles. Polymer Chemistry, 9(27), https://doi.org/10.1039/c8py00707a

We report a facile and versatile strategy for the bespoke fabrication of macro- and mesoporous block copolymer microparticles. A clean synthetic route, RAFT dispersion polymerisation in supercritical carbon dioxide (scCO2), is used to generate block... Read More about A facile route to bespoke macro- and mesoporous block copolymer microparticles.

Block copolymer synthesis by controlled/living radical polymerisation in heterogeneous systems (2016)
Journal Article
Jennings, J., He, G., Howdle, S. M., & Zetterlund, P. B. (in press). Block copolymer synthesis by controlled/living radical polymerisation in heterogeneous systems. Chemical Society Reviews, https://doi.org/10.1039/c6cs00253f

Nanostructured soft materials open up new opportunities in material design and application, and block copolymer self-assembly is one particularly powerful phenomenon that can be exploited for their synthesis. The advent of controlled/living radical p... Read More about Block copolymer synthesis by controlled/living radical polymerisation in heterogeneous systems.