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An antiferromagnetically coupled heterometal Cu6Fe wheel

Saiki, Ryo; Yoshida, Norifumi; Hoshino, Norihisa; Newton, Graham N.; Shiga, Takuya; Oshio, Hiroki

Authors

Ryo Saiki

Norifumi Yoshida

Norihisa Hoshino

Takuya Shiga

Hiroki Oshio



Abstract

A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6- (OH)2(OCH3)4](NO3)3¢6H2O (1¢6H2O) (H2L = 1-(2-pyridine) 3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals that the heptanuclear wheel cluster consists of a central Fe(III) ion surrounded by six Cu(II) ions, linked through methoxo- and hydroxo-bridges. Cryomagnetic studies indicate intramolecular antiferromagnetic interactions were operative.

Citation

Saiki, R., Yoshida, N., Hoshino, N., Newton, G. N., Shiga, T., & Oshio, H. (2017). An antiferromagnetically coupled heterometal Cu6Fe wheel. Chemistry Letters, 46(8), doi:10.1246/cl.170365. ISSN 0366-7022

Journal Article Type Article
Acceptance Date May 21, 2017
Online Publication Date May 30, 2017
Publication Date Aug 1, 2017
Deposit Date Jul 19, 2017
Journal Chemistry Letters
Print ISSN 0366-7022
Electronic ISSN 0366-7022
Publisher Chemical Society of Japan
Peer Reviewed Peer Reviewed
Volume 46
Issue 8
DOI https://doi.org/10.1246/cl.170365
Keywords Heterometal polynuclear complex ; Wheel complex ; Antiferromagnetic interaction
Public URL http://eprints.nottingham.ac.uk/id/eprint/44251
Publisher URL http://www.journal.csj.jp/doi/abs/10.1246/cl.170365?af=R
Copyright Statement Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf
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