Ryo Saiki
An antiferromagnetically coupled heterometal Cu6Fe wheel
Saiki, Ryo; Yoshida, Norifumi; Hoshino, Norihisa; Newton, Graham N.; Shiga, Takuya; Oshio, Hiroki
Authors
Norifumi Yoshida
Norihisa Hoshino
GRAHAM NEWTON GRAHAM.NEWTON@NOTTINGHAM.AC.UK
Associate Professor
Takuya Shiga
Hiroki Oshio
Abstract
A heterometal Cu6Fe wheel molecule, [CuII6FeIII(HL)6- (OH)2(OCH3)4](NO3)3¢6H2O (1¢6H2O) (H2L = 1-(2-pyridine) 3-(2-pyrrole)acetylacetone) was synthesized by the one-pot reaction of H2L with copper and iron sources. X-ray structural analysis reveals that the heptanuclear wheel cluster consists of a central Fe(III) ion surrounded by six Cu(II) ions, linked through methoxo- and hydroxo-bridges. Cryomagnetic studies indicate intramolecular antiferromagnetic interactions were operative.
Citation
Saiki, R., Yoshida, N., Hoshino, N., Newton, G. N., Shiga, T., & Oshio, H. (2017). An antiferromagnetically coupled heterometal Cu6Fe wheel. Chemistry Letters, 46(8), https://doi.org/10.1246/cl.170365
Journal Article Type | Article |
---|---|
Acceptance Date | May 21, 2017 |
Online Publication Date | May 30, 2017 |
Publication Date | Aug 1, 2017 |
Deposit Date | Jul 19, 2017 |
Publicly Available Date | Mar 29, 2024 |
Journal | Chemistry Letters |
Print ISSN | 0366-7022 |
Electronic ISSN | 0366-7022 |
Publisher | Chemical Society of Japan |
Peer Reviewed | Peer Reviewed |
Volume | 46 |
Issue | 8 |
DOI | https://doi.org/10.1246/cl.170365 |
Keywords | Heterometal polynuclear complex ; Wheel complex ; Antiferromagnetic interaction |
Public URL | https://nottingham-repository.worktribe.com/output/875967 |
Publisher URL | http://www.journal.csj.jp/doi/abs/10.1246/cl.170365?af=R |
You might also like
Enflurane Additive for Sodium Negative Electrodes
(2022)
Journal Article
A Mixed‐Addenda Mo/W Organofunctionalised Hybrid Polyoxometalate
(2022)
Journal Article
Downloadable Citations
About Repository@Nottingham
Administrator e-mail: digital-library-support@nottingham.ac.uk
This application uses the following open-source libraries:
SheetJS Community Edition
Apache License Version 2.0 (http://www.apache.org/licenses/)
PDF.js
Apache License Version 2.0 (http://www.apache.org/licenses/)
Font Awesome
SIL OFL 1.1 (http://scripts.sil.org/OFL)
MIT License (http://opensource.org/licenses/mit-license.html)
CC BY 3.0 ( http://creativecommons.org/licenses/by/3.0/)
Powered by Worktribe © 2024
Advanced Search