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A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases

Perotto, Carlo U.; Marshall, George; Jones, Graham J.; Lewis, William; McMaster, Jonathan; Schröder, Martin

Authors

Carlo U. Perotto

GEORGE MARSHALL GEORGE.MARSHALL@NOTTINGHAM.AC.UK
Business Science Fellow- Co-Ordination Chemistry (Bsf)

Graham J. Jones

William Lewis william.lewis@nottingham.ac.uk

Martin Schröder M.Schroder@man.ac.uk



Abstract

Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases.

Journal Article Type Article
Publication Date Sep 30, 2015
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 51
APA6 Citation Perotto, C. U., Marshall, G., Jones, G. J., Lewis, W., McMaster, J., & Schröder, M. (2015). A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases. Chemical Communications, 51, doi:10.1039/c5cc05881c
DOI https://doi.org/10.1039/c5cc05881c
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC05881C#!divAbstract
Copyright Statement Copyright information regarding this work can be found at the following address: http://eprints.nottingh.../end_user_agreement.pdf

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A Ni(I)Fe(II) analogue of the Ni-L state of the Active Site of the [NiFe] Hydrogenases.pdf (210 Kb)
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Copyright Statement
Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf





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