A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases

Perotto, Carlo U.; Marshall, George; Jones, Graham J.; Lewis, William; McMaster, Jonathan; Schr�der, Martin

Abstract

Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases.

Citation

Perotto, C. U., Marshall, G., Jones, G. J., Lewis, W., McMaster, J., & Schröder, M. (2015). A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases. Chemical Communications, 51, https://doi.org/10.1039/c5cc05881c

• Journal Article Type: Article
• Publication Date: Sep 30, 2015
• Deposit Date: Nov 30, 2015
• Publicly Available Date: Nov 30, 2015
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 51
• DOI: https://doi.org/10.1039/c5cc05881c
• Public URL: https://nottingham-repository.worktribe.com/output/760231
• Publisher URL: http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC05881C#!divAbstract