Skip to main content

Research Repository

Advanced Search

Hygrothermal simulation-informed design of mesoporous desiccants for optimised energy efficiency of mixed mode air conditioning systems

Sarce Thomann, Fernando; Hall, Matthew R.; Mokaya, Robert; Stevens, Lee A.

Authors

Fernando Sarce Thomann emxfs@nottingham.ac.uk

Matthew R. Hall Matthew.Hall@nottingham.ac.uk

Robert Mokaya r.mokaya@nottingham.ac.uk

Lee A. Stevens enzlas@exmail.nottingham.ac.uk



Abstract

This paper describes an optimization technique using hygrothermal numerical modelling to determine an ideal and unknown isotherm in order to inform the design of optimised mesoporous desiccants. Their suitability for passive humidity buffering as well as their impact on energy efficiency was assessed when assisting a mixed mode air-conditioning (AC) system. Three clear stages of water vapour adsorption were found that strongly correspond to the Dw gradient when assessing the kinetics of adsorption and exchange rates for periodic moisture loads. Consistent agreement was found between the latent heat of dehumidification used by the AC system and the desiccant decay time after successive sorption loop cycles. This confirmed the material's suitability for specific applications and was found to be highly sensitive to the portion of the isotherm between φi,L - φi,U (Dw gradient), compared with full adsorption capacity (total w) when assessing total energy consumption. The experimental results of sorption kinetics appeared to be slightly underestimated between the Dw gradient and the response time to reach equilibrium moisture content (EMC). The major underestimations were found to be consistent with the kinetics of adsorption/desorption when analysing their significance based on w differences. These were largely attributed to a combination of adsorption kinetics (time-response) and adsorption/desorption hysteresis. However, this was not evident when comparing long-term experimental data and numerical estimations for water vapour sorption isotherms, since numerical model accurately predicted them. This suggests that both adsorption kinetics and the scanning curve prediction, within a hysteresis loop, are not accurately represented by current hygrothermal models and are hence a priority for future research.

Journal Article Type Article
Publication Date Dec 7, 2015
Journal Journal of Materials Chemistry A
Print ISSN 2050-7488
Electronic ISSN 2050-7496
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 3
Issue 33
Pages 17290-17303
APA6 Citation Sarce Thomann, F., Hall, M. R., Mokaya, R., & Stevens, L. A. (2015). Hygrothermal simulation-informed design of mesoporous desiccants for optimised energy efficiency of mixed mode air conditioning systems. Journal of Materials Chemistry A, 3(33), 17290-17303. https://doi.org/10.1039/c5ta05162b
DOI https://doi.org/10.1039/c5ta05162b
Keywords hygrothermal modelling; water vapour isotherm; desiccants design; mesoporous; air conditioning; energy efficiency
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2015/TA/C5TA05162B#!divAbstract
Copyright Statement Copyright information regarding this work can be found at the following address: http://creativecommons.org/licenses/by/4.0
Additional Information : This document is Similarity Check deposited; : The Royal Society of Chemistry has an exclusive publication licence for this journal; OPEN ACCESS: This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0); : Single-blind; : Received 9 July 2015; Accepted 27 July 2015; Accepted Manuscript published 27 July 2015; Advance Article published 30 July 2015; Version of Record published 11 August 2015

Files

Hygrothermal simulation-informed design of mesoporous desiccants for optimised energy efficiency of mixed mode air conditioning systems.pdf (1.7 Mb)
PDF

Copyright Statement
Copyright information regarding this work can be found at the following address: http://creativecommons.org/licenses/by/4.0





You might also like



Downloadable Citations

;