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Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors

Penders, Inès G. T. M.; Amara, Zacharias; Horvath, Raphael; Rossen, Kai; Poliakoff, Martyn; George, Michael W.

Authors

Inès G. T. M. Penders

Zacharias Amara

Raphael Horvath

Kai Rossen



Abstract

The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH–H2O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for moderately efficient desymmetrisation.

Journal Article Type Article
Journal RSC Advances
Print ISSN 2046-2069
Electronic ISSN 2046-2069
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 5
Issue 9
APA6 Citation Penders, I. G. T. M., Amara, Z., Horvath, R., Rossen, K., Poliakoff, M., & George, M. W. (in press). Photocatalytic hydroxylation of arylboronic acids using continuous flow reactors. RSC Advances, 5(9), https://doi.org/10.1039/c4ra15588b
DOI https://doi.org/10.1039/c4ra15588b
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2015/RA/C4RA15588B#!divAbstract
Copyright Statement Copyright information regarding this work can be found at the following address: http://eprints.nottingh.../end_user_agreement.pdf

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Copyright Statement
Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf





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