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Structural chemistry of metal coordination complexes at high pressure

Schröder, Martin

Authors

Martin Schröder M.Schroder@man.ac.uk



Abstract

The application of pressures of up to about 10 GPa may induce significant geometric, configurational, conformational and packing changes in molecular solids. This review highlights and describes recent advances in high pressure studies of coordination complexes, many of which have been conducted at synchrotrons or other central facilities. The main focus is on the wide range of geometric changes which occur with pressure. In some cases these changes have associated physical effects, and the review describes materials exhibiting negative linear compressibility, spin cross-over phenomena, magnetism and molecular conduction, as well as detailing the exciting possibilities for future developments in this area of research.

Journal Article Type Article
Publication Date Oct 1, 2014
Journal Coordination Chemistry Reviews
Print ISSN 0010-8545
Electronic ISSN 0010-8545
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 277
APA6 Citation Schröder, M. (2014). Structural chemistry of metal coordination complexes at high pressure. Coordination Chemistry Reviews, 277, doi:10.1016/j.ccr.2014.04.004
DOI https://doi.org/10.1016/j.ccr.2014.04.004
Keywords Synchrotron science; High pressure crystallography; Phase changes; Metal-organic complexes; Organometallic compounds; Supramolecular chemistry
Publisher URL http://www.sciencedirect.com/science/article/pii/S0010854514001167
Copyright Statement Copyright information regarding this work can be found at the following address: http://creativecommons.org/licenses/by-nc-nd/4.0

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Revised HP CCR Paper 03-04-14.pdf (621 Kb)
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Copyright Statement
Copyright information regarding this work can be found at the following address: http://creativecommons.org/licenses/by-nc-nd/4.0





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