Transition metal decorated soft nanomaterials through modular self-assembly of an asymmetric hybrid polyoxometalate

Hampson, Elizabeth; Cameron, Jamie M.; Watts, Julie A.; Newton, Graham N.

Abstract

An asymmetrically functionalised Wells–Dawson organic–inorganic hybrid polyoxometalate has been post-functionalised by Pt2+ coordination, and demonstrates self-assembly into surface-decorated micellar nanostructures. This multifunctional hybrid material is found to be a redox-active soft nanomaterial and demonstrates a new molecular design strategy with potential for applications in photo- or electro-catalysis.

Citation

Hampson, E., Cameron, J. M., Watts, J. A., & Newton, G. N. (2020). Transition metal decorated soft nanomaterials through modular self-assembly of an asymmetric hybrid polyoxometalate. Chemical Communications, 56, 8237-8240. https://doi.org/10.1039/d0cc03554h

• Journal Article Type: Article
• Acceptance Date: Jun 10, 2020
• Online Publication Date: Jun 12, 2020
• Publication Date: Jul 28, 2020
• Deposit Date: Jul 1, 2020
• Publicly Available Date: Jul 2, 2020
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 56
• Pages: 8237-8240
• DOI: https://doi.org/10.1039/d0cc03554h
• Keywords: Materials Chemistry; Electronic, Optical and Magnetic Materials; General Chemistry; Surfaces, Coatings and Films; Metals and Alloys; Ceramics and Composites; Catalysis
• Public URL: https://nottingham-repository.worktribe.com/output/4693158
• Publisher URL: https://pubs.rsc.org/en/content/articlelanding/2020/CC/D0CC03554H#!divAbstract
• Additional Information: : This document is Similarity Check deposited; : Supplementary Information; : Jamie M. Cameron (ORCID); : Graham N. Newton (ORCID); : Graham N. Newton (ResearcherID); : Authors can choose between single-blind and double-blind peer review; : Received 18 May 2020; Accepted 10 June 2020; Accepted Manuscript published 12 June 2020; Advance Article published 19 June 2020