Cyanide-Bridged Decanuclear Cobalt–Iron Cage

Oshio, Hiroki; Shiga, Takuya; Newton, Graham N.; Tetsuka, Tamaki; Nihei, Masayuki; Sakai, Kanae; Sekine, Yoshihiro

Abstract

A cyanide-bridged decanuclear [Co6Fe4] cluster was synthesized by a one-pot reaction, and the magnetic properties and electronic configuration were investigated. The complex displayed thermally controlled electron-transfer-coupled spin transition (ETCST) behavior between CoIII low-spin–NC–FeII low-spin and CoII high-spin–NC–FeIII low-spin states, as confirmed by single-crystal X-ray, magnetic, and Mössbauer analyses.

Citation

Oshio, H., Shiga, T., Newton, G. N., Tetsuka, T., Nihei, M., Sakai, K., & Sekine, Y. (2014). Cyanide-Bridged Decanuclear Cobalt–Iron Cage. Inorganic Chemistry, 53(12), 5899-5901. https://doi.org/10.1021/ic500964m

• Journal Article Type: Article
• Acceptance Date: Jun 1, 2014
• Online Publication Date: Jun 3, 2014
• Publication Date: Jun 16, 2014
• Deposit Date: Feb 26, 2020
• Publicly Available Date: Apr 29, 2020
• Journal: Inorganic Chemistry
• Print ISSN: 0020-1669
• Electronic ISSN: 1520-510X
• Publisher: American Chemical Society
• Peer Reviewed: Peer Reviewed
• Volume: 53
• Issue: 12
• Pages: 5899-5901
• DOI: https://doi.org/10.1021/ic500964m
• Keywords: Physical and Theoretical Chemistry; Inorganic Chemistry
• Public URL: https://nottingham-repository.worktribe.com/output/4037874
• Publisher URL: https://pubs.acs.org/doi/10.1021/ic500964m
• Additional Information: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by t he publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/ic500964m