Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers

Abstract

Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.

Citation

Marco, A. B., Cortizo-Lacalle, D., Perez-Miqueo, I., Valenti, G., Boni, A., Plas, J., …Mateo-Alonso, A. (2017). Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers. Angewandte Chemie International Edition, 56(24), 6946-6951. https://doi.org/10.1002/anie.201700271

• Journal Article Type: Article
• Acceptance Date: Mar 20, 2017
• Online Publication Date: Mar 20, 2017
• Publication Date: Jun 6, 2017
• Deposit Date: Mar 5, 2019
• Publicly Available Date: Mar 21, 2019
• Journal: Angewandte Chemie International Edition
• Print ISSN: 1433-7851
• Electronic ISSN: 1521-3773
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 56
• Issue: 24
• Pages: 6946-6951
• DOI: https://doi.org/10.1002/anie.201700271
• Keywords: Carbon nanostructures; Materials science; Nanocarbons; Organic frameworks; Twisted aromatic systems
• Public URL: https://nottingham-repository.worktribe.com/output/1610250
• Publisher URL: https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201700271