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Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers

Marco, A. Belen; Cortizo-Lacalle, Diego; Perez-Miqueo, Iñigo; Valenti, Giovanni; Boni, Alessandro; Plas, Jan; Strutyński, Karol; De Feyter, Steven; Paolucci, Francesco; Montes, Mario; Khlobystov, Andrei N.; Melle-Franco, Manuel; Mateo-Alonso, Aurelio

Authors

A. Belen Marco

Diego Cortizo-Lacalle

Iñigo Perez-Miqueo

Giovanni Valenti

Alessandro Boni

Jan Plas

Karol Strutyński

Steven De Feyter

Francesco Paolucci

Mario Montes

Manuel Melle-Franco

Aurelio Mateo-Alonso



Abstract

Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.

Journal Article Type Article
Publication Date Jun 6, 2017
Journal Angewandte Chemie International Edition
Print ISSN 1433-7851
Electronic ISSN 1521-3773
Publisher Wiley
Peer Reviewed Peer Reviewed
Volume 56
Issue 24
Pages 6946-6951
APA6 Citation Marco, A. B., Cortizo-Lacalle, D., Perez-Miqueo, I., Valenti, G., Boni, A., Plas, J., …Mateo-Alonso, A. (2017). Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers. Angewandte Chemie International Edition, 56(24), 6946-6951. https://doi.org/10.1002/anie.201700271
DOI https://doi.org/10.1002/anie.201700271
Keywords Carbon nanostructures; Materials science; Nanocarbons; Organic frameworks; Twisted aromatic systems
Publisher URL https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201700271

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