MATTHEW CLIFFE Matthew.Cliffe@nottingham.ac.uk
Associate Professor
Strongly coloured thiocyanate frameworks with perovskite-analogue structures
Cliffe, Matthew J.; Keyzer, Evan N.; Dunstan, Matthew T.; Ahmad, Shahab; De Volder, Michael F. L.; Deschler, Felix; Morris, Andrew J.; Grey, Clare P.
Authors
Evan N. Keyzer
Matthew T. Dunstan
Shahab Ahmad
Michael F. L. De Volder
Felix Deschler
Andrew J. Morris
Clare P. Grey
Abstract
We report the first examples of thiocyanate-based analogues of the cyanide Prussian Blue compounds, MIII[Bi(SCN)6], M= Fe, Cr, Sc. These compounds adopt the primitive cubic pcu topology and show strict cation order. Optical absorption measurements show these compounds have band gaps within the visible and near IR region, suggesting that they may be useful for applications where light harvesting is key, such as photocatalysis. We also show that Cr[Bi(SCN)6] can reversibly uptake water into its framework structure pointing towards the possibility of using these frameworks for host/guest chemistry.
Citation
Cliffe, M. J., Keyzer, E. N., Dunstan, M. T., Ahmad, S., De Volder, M. F. L., Deschler, F., …Grey, C. P. (2019). Strongly coloured thiocyanate frameworks with perovskite-analogue structures. Chemical Science, 10(3), 793-801. https://doi.org/10.1039/c8sc04082f
Journal Article Type | Article |
---|---|
Acceptance Date | Oct 25, 2018 |
Online Publication Date | Oct 26, 2018 |
Publication Date | Jan 21, 2019 |
Deposit Date | Nov 8, 2018 |
Publicly Available Date | Nov 8, 2018 |
Journal | Chemical Science |
Print ISSN | 2041-6520 |
Electronic ISSN | 2041-6539 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 10 |
Issue | 3 |
Pages | 793-801 |
DOI | https://doi.org/10.1039/c8sc04082f |
Keywords | General Chemistry |
Public URL | https://nottingham-repository.worktribe.com/output/1236202 |
Publisher URL | https://pubs.rsc.org/en/Content/ArticleLanding/2019/SC/C8SC04082F#!divAbstract |
Additional Information | : This document is Similarity Check deposited; : Supplementary Information; : Crystal Structure Data; : Matthew J. Cliffe (ORCID); : Evan N. Keyzer (ORCID); : Matthew T. Dunstan (ORCID); : Michael F. L. De Volder (ORCID); : Andrew J. Morris (ORCID); : Clare P. Grey (ORCID); : Single-blind; : Received 13 September 2018; Accepted 25 October 2018; Accepted Manuscript published 26 October 2018; Advance Article published 6 November 2018 |
Files
c8sc04082f
(3 Mb)
PDF
Publisher Licence URL
https://creativecommons.org/licenses/by/3.0/
You might also like
Non-collinear magnetism in the post-perovskite thiocyanate frameworks CsM(NCS)3
(2023)
Journal Article
One-dimensional alignment of defects in a flexible metal-organic framework
(2023)
Journal Article
Low-Dimensional Metal-Organic Magnets as a Route toward the S = 2 Haldane Phase
(2023)
Journal Article
Slow magnetic relaxation in Fe(ii) m-terphenyl complexes
(2022)
Journal Article
Downloadable Citations
About Repository@Nottingham
Administrator e-mail: digital-library-support@nottingham.ac.uk
This application uses the following open-source libraries:
SheetJS Community Edition
Apache License Version 2.0 (http://www.apache.org/licenses/)
PDF.js
Apache License Version 2.0 (http://www.apache.org/licenses/)
Font Awesome
SIL OFL 1.1 (http://scripts.sil.org/OFL)
MIT License (http://opensource.org/licenses/mit-license.html)
CC BY 3.0 ( http://creativecommons.org/licenses/by/3.0/)
Powered by Worktribe © 2024
Advanced Search