@article { , title = {Magnetic order in a metal thiocyanate perovskite-analogue}, abstract = {Metal thiocyanate perovskite-analogues are a growing class of materials, but although they contain paramagnetic cations there have been no reports of their magnetic properties. Due to the large separations between the paramagnetic cations, with a shortest through-bond distance of 15.1 Å, these materials might be expected to be good examples of paramagnets. In this communication we investigate the magnetic properties of a metal thiocyanate framework Cr[Bi(SCN)6]·xH2O. We find that Cr[Bi(SCN)6]·xH2O undergoes long-range magnetic order at TN = 4.0(2) K. We use neutron powder diffraction to determine that Cr[Bi(SCN)6]·xH2O has a MnO-type \{111\}cubic-ordering as its ground state, consistent with frustrated nearest- and next-nearest-neighbour antiferromagnetic interactions. This suggests that appropriate design of metal thiocyanate perovskite-analogue structures may reveal a rich vein of frustrated magnetism.}, doi = {10.1039/d2ce00649a}, eissn = {1466-8033}, journal = {CrystEngComm}, publicationstatus = {Published}, publisher = {Royal Society of Chemistry (RSC)}, url = {https://nottingham-repository.worktribe.com/output/8633867}, keyword = {Physical Sciences - Inorganic Chemistry, Condensed Matter Physics, General Materials Science, General Chemistry}, year = {2022}, author = {Cliffe, Matthew J. and Fabelo, Oscar and Cañadillas-Delgado, Laura} }